{"title":"调节 Ru 纳米粒子与 Nd2O3 之间的相互作用以增强氨分解产生的氢气","authors":"","doi":"10.1007/s11244-024-01926-8","DOIUrl":null,"url":null,"abstract":"<h3>Abstract</h3> <p>Development of highly active and stable catalysts for production of CO<sub>x</sub>-free hydrogen from ammonia is crucial for the use of ammonia as hydrogen carrier. Herein, Ru nanoparticles (NPs) on Nd<sub>2</sub>O<sub>3</sub> (Ru/Nd<sub>2</sub>O<sub>3</sub>) was prepared by different methods and investigated for NH<sub>3</sub> decomposition reaction. The dependence of the catalytic activity of Ru NPs on the Nd<sub>2</sub>O<sub>3</sub> on the interaction between Ru NPs and Nd<sub>2</sub>O<sub>3</sub> support was investigated in detail. The Ru/Nd<sub>2</sub>O<sub>3</sub> obtained from precipitation method exhibits a high hydrogen formation rate of 1548 mmol g<sub>cat</sub><sup>−1</sup> h<sup>−1</sup> at 450 °C, which is high than that of the Ru/Nd<sub>2</sub>O<sub>3</sub> analogue from milling method and comparable with many efficient oxides supported Ru catalysts reported previously. As revealed by various characterization techniques, the high activity of Ru/Nd<sub>2</sub>O<sub>3</sub> obtained from precipitation method can be attributed to the enhanced interaction between Ru NPs and Nd<sub>2</sub>O<sub>3</sub>. The Ru NPs in Ru/Nd<sub>2</sub>O<sub>3</sub> analogue with enhanced the metal-support interaction can modulate electronic structure and facilitate the activation and decomposition of NH<sub>3</sub>. Therefore, Ru/Nd<sub>2</sub>O<sub>3</sub> obtained from precipitation method exhibited significantly improved activity and intrinsic activity for NH<sub>3</sub> decomposition. This study provides promise for the design of efficient Ru/Nd<sub>2</sub>O<sub>3</sub> catalyst for NH<sub>3</sub> decomposition reaction by tuning the metal–support interaction of catalysts.</p>","PeriodicalId":801,"journal":{"name":"Topics in Catalysis","volume":"44 1","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2024-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Tuning the Interaction Between Ru Nanoparticles and Nd2O3 to Enhance Hydrogen Formation from Ammonia Decomposition\",\"authors\":\"\",\"doi\":\"10.1007/s11244-024-01926-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3>Abstract</h3> <p>Development of highly active and stable catalysts for production of CO<sub>x</sub>-free hydrogen from ammonia is crucial for the use of ammonia as hydrogen carrier. Herein, Ru nanoparticles (NPs) on Nd<sub>2</sub>O<sub>3</sub> (Ru/Nd<sub>2</sub>O<sub>3</sub>) was prepared by different methods and investigated for NH<sub>3</sub> decomposition reaction. The dependence of the catalytic activity of Ru NPs on the Nd<sub>2</sub>O<sub>3</sub> on the interaction between Ru NPs and Nd<sub>2</sub>O<sub>3</sub> support was investigated in detail. The Ru/Nd<sub>2</sub>O<sub>3</sub> obtained from precipitation method exhibits a high hydrogen formation rate of 1548 mmol g<sub>cat</sub><sup>−1</sup> h<sup>−1</sup> at 450 °C, which is high than that of the Ru/Nd<sub>2</sub>O<sub>3</sub> analogue from milling method and comparable with many efficient oxides supported Ru catalysts reported previously. As revealed by various characterization techniques, the high activity of Ru/Nd<sub>2</sub>O<sub>3</sub> obtained from precipitation method can be attributed to the enhanced interaction between Ru NPs and Nd<sub>2</sub>O<sub>3</sub>. The Ru NPs in Ru/Nd<sub>2</sub>O<sub>3</sub> analogue with enhanced the metal-support interaction can modulate electronic structure and facilitate the activation and decomposition of NH<sub>3</sub>. Therefore, Ru/Nd<sub>2</sub>O<sub>3</sub> obtained from precipitation method exhibited significantly improved activity and intrinsic activity for NH<sub>3</sub> decomposition. This study provides promise for the design of efficient Ru/Nd<sub>2</sub>O<sub>3</sub> catalyst for NH<sub>3</sub> decomposition reaction by tuning the metal–support interaction of catalysts.</p>\",\"PeriodicalId\":801,\"journal\":{\"name\":\"Topics in Catalysis\",\"volume\":\"44 1\",\"pages\":\"\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-03-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Topics in Catalysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s11244-024-01926-8\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Topics in Catalysis","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s11244-024-01926-8","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Tuning the Interaction Between Ru Nanoparticles and Nd2O3 to Enhance Hydrogen Formation from Ammonia Decomposition
Abstract
Development of highly active and stable catalysts for production of COx-free hydrogen from ammonia is crucial for the use of ammonia as hydrogen carrier. Herein, Ru nanoparticles (NPs) on Nd2O3 (Ru/Nd2O3) was prepared by different methods and investigated for NH3 decomposition reaction. The dependence of the catalytic activity of Ru NPs on the Nd2O3 on the interaction between Ru NPs and Nd2O3 support was investigated in detail. The Ru/Nd2O3 obtained from precipitation method exhibits a high hydrogen formation rate of 1548 mmol gcat−1 h−1 at 450 °C, which is high than that of the Ru/Nd2O3 analogue from milling method and comparable with many efficient oxides supported Ru catalysts reported previously. As revealed by various characterization techniques, the high activity of Ru/Nd2O3 obtained from precipitation method can be attributed to the enhanced interaction between Ru NPs and Nd2O3. The Ru NPs in Ru/Nd2O3 analogue with enhanced the metal-support interaction can modulate electronic structure and facilitate the activation and decomposition of NH3. Therefore, Ru/Nd2O3 obtained from precipitation method exhibited significantly improved activity and intrinsic activity for NH3 decomposition. This study provides promise for the design of efficient Ru/Nd2O3 catalyst for NH3 decomposition reaction by tuning the metal–support interaction of catalysts.
期刊介绍：
Topics in Catalysis publishes topical collections in all fields of catalysis which are composed only of invited articles from leading authors. The journal documents today’s emerging and critical trends in all branches of catalysis. Each themed issue is organized by renowned Guest Editors in collaboration with the Editors-in-Chief. Proposals for new topics are welcome and should be submitted directly to the Editors-in-Chief.
The publication of individual uninvited original research articles can be sent to our sister journal Catalysis Letters. This journal aims for rapid publication of high-impact original research articles in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis.
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