盐酸多巴胺液体选择性电极的构建

Rana A. Hammza
{"title":"盐酸多巴胺液体选择性电极的构建","authors":"Rana A. Hammza","doi":"10.22401/anjs.27.1.03","DOIUrl":null,"url":null,"abstract":"Three liquid selective electrodes were synthesized based on particle pair to selective dopamine chloride. The construction electrodes consist of phosphomolybdicacid (dopamine), di-n-butyl phosphate, Di-n-butyl phthalate, and di-octylphenyl phosphonate as plasticizers materials. The construction of preparing probes was examined potentially with successes Nernstain response around 52.50 and 50. 50 mV/decade for electrodes on both DBPH and DOPH were as plasticizers, respectively. The most direct ranges concentrations of dopamine in drug form were found to be around 2.5×10-5-1.0×10-2 for DBPH and 4.30×10-5 -1.0×10-1 M for DOPH. The detection limits were reached to 2.31×10-6 in DBPH and 5. 63×10-6 M in DOPH electrode type. While third electrode relied on di-n-butyl phosphate (DPH), a non-Nernstain equivalent of around 19.10 mV/decade with a range of concentration about 2.2×10-5 -1.0×10-1 with a detection limit equivalent to 6.35×10-6. The pH values in the experimental application were asses to obtain the best determination of dopamine concentration at 10-3M. The optimisation of both electrodes DBPH and DOPH achieved good agreements to lifetime, selectivity, potentiometric techniques and accuracy of measurements. At the same time the standard expansion, various standard expansions and potentiometric titration result in an immediate strategy for the assurance of dopamine in drug form.","PeriodicalId":7494,"journal":{"name":"Al-Nahrain Journal of Science","volume":"29 22","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Construction of Dopamine Hydrochloride Liquid Selective Electrodes\",\"authors\":\"Rana A. Hammza\",\"doi\":\"10.22401/anjs.27.1.03\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Three liquid selective electrodes were synthesized based on particle pair to selective dopamine chloride. The construction electrodes consist of phosphomolybdicacid (dopamine), di-n-butyl phosphate, Di-n-butyl phthalate, and di-octylphenyl phosphonate as plasticizers materials. The construction of preparing probes was examined potentially with successes Nernstain response around 52.50 and 50. 50 mV/decade for electrodes on both DBPH and DOPH were as plasticizers, respectively. The most direct ranges concentrations of dopamine in drug form were found to be around 2.5×10-5-1.0×10-2 for DBPH and 4.30×10-5 -1.0×10-1 M for DOPH. The detection limits were reached to 2.31×10-6 in DBPH and 5. 63×10-6 M in DOPH electrode type. While third electrode relied on di-n-butyl phosphate (DPH), a non-Nernstain equivalent of around 19.10 mV/decade with a range of concentration about 2.2×10-5 -1.0×10-1 with a detection limit equivalent to 6.35×10-6. The pH values in the experimental application were asses to obtain the best determination of dopamine concentration at 10-3M. The optimisation of both electrodes DBPH and DOPH achieved good agreements to lifetime, selectivity, potentiometric techniques and accuracy of measurements. At the same time the standard expansion, various standard expansions and potentiometric titration result in an immediate strategy for the assurance of dopamine in drug form.\",\"PeriodicalId\":7494,\"journal\":{\"name\":\"Al-Nahrain Journal of Science\",\"volume\":\"29 22\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Al-Nahrain Journal of Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22401/anjs.27.1.03\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Al-Nahrain Journal of Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22401/anjs.27.1.03","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

以颗粒对为基础合成了三种液体选择性电极,用于选择氯化多巴胺。构建的电极由磷钼酸(多巴胺)、磷酸二正丁酯、邻苯二甲酸二正丁酯和膦酸二辛基苯酯作为增塑剂材料组成。研究发现,在 52.50 和 50.50 mV/decade 左右的成功 Nernstain 反应下,制备探针的构造是可行的。以 DBPH 和 DOPH 为增塑剂的电极的 Nernstain 反应分别为 52.50 和 50.50 mV/decade。发现药物形式的多巴胺最直接的浓度范围为:DBPH 约为 2.5×10-5-1.0×10-2 M,DOPH 约为 4.30×10-5 -1.0×10-1 M。DBPH 和 DOPH 的检出限分别为 2.31×10-6 和 5.63×10-6 M。63×10-6 M。第三种电极依靠磷酸二正丁酯(DPH),其非染色当量约为 19.10 mV/decade,浓度范围约为 2.2×10-5 -1.0×10-1 ,检测限相当于 6.35×10-6。实验应用中对 pH 值进行了评估,以获得 10-3M 的多巴胺浓度的最佳测定值。通过对 DBPH 和 DOPH 两种电极进行优化,在寿命、选择性、电位技术和测量精度方面都取得了良好的一致。同时,通过标准扩展、各种标准扩展和电位滴定,可以立即确定药物形式的多巴胺。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Construction of Dopamine Hydrochloride Liquid Selective Electrodes
Three liquid selective electrodes were synthesized based on particle pair to selective dopamine chloride. The construction electrodes consist of phosphomolybdicacid (dopamine), di-n-butyl phosphate, Di-n-butyl phthalate, and di-octylphenyl phosphonate as plasticizers materials. The construction of preparing probes was examined potentially with successes Nernstain response around 52.50 and 50. 50 mV/decade for electrodes on both DBPH and DOPH were as plasticizers, respectively. The most direct ranges concentrations of dopamine in drug form were found to be around 2.5×10-5-1.0×10-2 for DBPH and 4.30×10-5 -1.0×10-1 M for DOPH. The detection limits were reached to 2.31×10-6 in DBPH and 5. 63×10-6 M in DOPH electrode type. While third electrode relied on di-n-butyl phosphate (DPH), a non-Nernstain equivalent of around 19.10 mV/decade with a range of concentration about 2.2×10-5 -1.0×10-1 with a detection limit equivalent to 6.35×10-6. The pH values in the experimental application were asses to obtain the best determination of dopamine concentration at 10-3M. The optimisation of both electrodes DBPH and DOPH achieved good agreements to lifetime, selectivity, potentiometric techniques and accuracy of measurements. At the same time the standard expansion, various standard expansions and potentiometric titration result in an immediate strategy for the assurance of dopamine in drug form.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信