T. A. Poсhodina, N. Kulinich, V. V. Komar, O. Y. Smirnova, N. Krutko
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引用次数: 0
摘要
研究了以脂肪族胺或防腐颜料混合物改性的环氧粉末涂料为基础的涂层(厚度为 70 微米)在氯化钠溶液和盐雾作用下的耐腐蚀性。研究表明,随着初始环氧低聚物分子量的增加,以及含有极性基团的化学吸附性脂肪族胺的加入,氯化钠溶液对涂层材料的渗透性降低。研究发现,涂层性能的变化是由于聚合物形成了具有不同交联频率的空间结构。研究表明,在涂料成分中引入防腐颜料混合物后,与基础成分相比,涂料的保护性能显著提高,物理和机械性能也得到了很好的保持。在氯化钠溶液中测试 9000 小时后,涂料的强度特性比原来降低了约 10-12%。根据涂层在盐雾作用下的测试结果,可以看出所开发的环氧粉末涂料可以在大气腐蚀性较强的 C 5-1 类环境中使用,包括直接在金属表面涂装(直接涂装到金属),而无需对金属表面进行多道工序的涂装准备。
Anti-corrosion resistance of coatings based on powder epoxy paints containing modifiers
The corrosion resistance of coatings (thickness 70 µm) based on epoxy powder paints modified with aliphatic amine or a mixture of anticorrosive pigments to the action of sodium chloride solution and salt spray has been studied. It is showed that with the increase of molecuar weight of initial epoxy oligomer and also at the incorporation of chemisorbing alifatic amine, containing polar groups, to the decrease in the permeability of the sodium chloride solution into the coating material is observed. It has been established that the observed changes in the properties of the coatings are due to the formation of a spatial structure of the polymer with different cross-link frequencies. It is shown that the introduction of a mixture of anti-corrosion pigments into the composition of paints provides a significant increase in the protective properties of coatings and a high preservation of the physical and mechanical properties of coatings in comparison with the base compositions. For 9000 hours of testing in a sodium chloride solution, the strength characteristics of the coatings decrease by about 10–12 % from the original ones. Based on the results of tests of coatings to the action of salt spray, the possibility of using the developed epoxy powder paints for operation in environments of a high atmospheric-corrosive category – C 5–1, including the application of coatings directly on a metal surface (Direct to metal) without multi-stage preparation of the metal surface for painting, is shown.