K. Oreszczuk, W. Pacuski, A. Rodek, Mateusz Raczyński, T. Kazimierczuk, K. Nogajewski, T. Taniguchi, Kenji Watanabe, M. Potemski, P. Kossacki
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Short excitonic lifetimes of MoSe2 monolayers grown by molecular beam epitaxy on the hexagonal boron nitride
We present a time-resolved optical study of recently developed narrow-line MoSe2 monolayers grown on hexagonal boron nitride with means of Molecular Beam Epitaxy. We find that the photoluminescence decay times are significantly shorter than in the case of the exfoliated samples, even below one picosecond. Such a short timescale requires measurements with better resolution than achievable with a streak camera. Therefore, we employ an Excitation Correlation Spectroscopy (ECS) pump-probe technique. This approach allows us to identify two distinct non-radiative recombination channels attributed to lattice imperfections. The first channel is active at helium temperatures. It reduces the lifetime of the neutral exciton to below one picosecond. The second channel becomes active at elevated temperatures, further shortening the lifetimes of both neutral and charged exciton. The high effectiveness of both radiative and non-radiative recombination makes epitaxial MoSe2 a promising material for ultrafast optoelectronics.
期刊介绍:
ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.