Sarah C Gillespie, Marco van der Laan, D. Poonia, Sourav Maiti, Sachin Kinge, L. Siebbeles, Peter Schall
{"title":"TMDC/TMDC 和 TMDC/perovskite 异质结构中电荷和能量转移的光学特征","authors":"Sarah C Gillespie, Marco van der Laan, D. Poonia, Sourav Maiti, Sachin Kinge, L. Siebbeles, Peter Schall","doi":"10.1088/2053-1583/ad341c","DOIUrl":null,"url":null,"abstract":"\n Heterostructures based on two-dimensional transition metal dichalcogenides (TMDC) are highly intriguing materials because of the layers' pronounced excitonic properties and their nontrivial contributions to the heterostructure (HS). These heterostructures exhibit unique properties that are not observed in either of the constituent components in isolation. Interlayer excitons, which are electron-hole pairs separated across the heterostructures, play a central role in determining these heterostructure properties and are of interest both fundamentally and for device applications. In recent years, a major focus has been on understanding and designing heterostructures composed of two or more TMDC materials. Less attention has been paid to heterostructures composed of one TMDC layer and a layer of perovskite material. A central challenge in the understanding of HS properties is that basic measurements such as optical spectroscopic analysis can be misinterpreted due to the complexity of the charge transfer dynamics. Addressing these aspects, this review presents an overview of the most common and insightful optical spectroscopic techniques used to study TMDC/TMDC and TMDC/halide perovskite HSs. Emphasis is placed on the interpretation of these measurements in terms of charge transfer and the formation of interlayer excitons. Recent advances have started to uncover highly interesting phenomena, and with improved understanding these heterostructures offer great potential for device applications such as photodetectors and miniaturized optics.","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"5 7","pages":""},"PeriodicalIF":5.4000,"publicationDate":"2024-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optical signatures of charge- and energy transfer in TMDC/TMDC and TMDC/perovskite heterostructures\",\"authors\":\"Sarah C Gillespie, Marco van der Laan, D. Poonia, Sourav Maiti, Sachin Kinge, L. Siebbeles, Peter Schall\",\"doi\":\"10.1088/2053-1583/ad341c\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n Heterostructures based on two-dimensional transition metal dichalcogenides (TMDC) are highly intriguing materials because of the layers' pronounced excitonic properties and their nontrivial contributions to the heterostructure (HS). These heterostructures exhibit unique properties that are not observed in either of the constituent components in isolation. Interlayer excitons, which are electron-hole pairs separated across the heterostructures, play a central role in determining these heterostructure properties and are of interest both fundamentally and for device applications. In recent years, a major focus has been on understanding and designing heterostructures composed of two or more TMDC materials. Less attention has been paid to heterostructures composed of one TMDC layer and a layer of perovskite material. A central challenge in the understanding of HS properties is that basic measurements such as optical spectroscopic analysis can be misinterpreted due to the complexity of the charge transfer dynamics. Addressing these aspects, this review presents an overview of the most common and insightful optical spectroscopic techniques used to study TMDC/TMDC and TMDC/halide perovskite HSs. Emphasis is placed on the interpretation of these measurements in terms of charge transfer and the formation of interlayer excitons. 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Optical signatures of charge- and energy transfer in TMDC/TMDC and TMDC/perovskite heterostructures
Heterostructures based on two-dimensional transition metal dichalcogenides (TMDC) are highly intriguing materials because of the layers' pronounced excitonic properties and their nontrivial contributions to the heterostructure (HS). These heterostructures exhibit unique properties that are not observed in either of the constituent components in isolation. Interlayer excitons, which are electron-hole pairs separated across the heterostructures, play a central role in determining these heterostructure properties and are of interest both fundamentally and for device applications. In recent years, a major focus has been on understanding and designing heterostructures composed of two or more TMDC materials. Less attention has been paid to heterostructures composed of one TMDC layer and a layer of perovskite material. A central challenge in the understanding of HS properties is that basic measurements such as optical spectroscopic analysis can be misinterpreted due to the complexity of the charge transfer dynamics. Addressing these aspects, this review presents an overview of the most common and insightful optical spectroscopic techniques used to study TMDC/TMDC and TMDC/halide perovskite HSs. Emphasis is placed on the interpretation of these measurements in terms of charge transfer and the formation of interlayer excitons. Recent advances have started to uncover highly interesting phenomena, and with improved understanding these heterostructures offer great potential for device applications such as photodetectors and miniaturized optics.
期刊介绍:
ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.