具有可回收骨架的形态稳定相变材料在储能和应用方面的最新进展

Yuan Jia, Yaoting Jiang, Yunshi Pan, Xinmei Zou, Qian Zhang, Xiaojian Gao, Jingxi Zhang, Kunyang Yu, Yingzi Yang, Yushi Liu
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引用次数: 0

摘要

随着全球人口的增长,能源短缺问题日益突出。相变材料(PCM)被认为是绿色高效的热能存储介质,但相变过程中体积不稳定造成的泄漏问题限制了其应用。用辅助材料封装 PCM 可以有效避免泄漏,但大多数辅助材料价格昂贵且消耗大量自然资源。碳材料是一种丰富的可再生资源,可用作制备形态稳定的 PCM 的经济而环保的支撑骨架。虽然很多研究人员已经开始使用可回收材料,特别是各种碳衍生物作为支撑骨架来制备形式稳定的 PCM,但目前还很少有人对使用可回收骨架的形式稳定 PCM 的制备方法、热物理性质和应用进行系统总结。具有可回收骨架的形态稳定 PCM 具有较高的蓄热能力和经过 2000 次热循环后仍具有良好的热物理性能稳定性,可用作绿色高效的蓄热材料。本综述研究了可回收骨架对热物理性质的影响,包括相变温度、潜热、热导率、过冷度和热循环可靠性。主要研究了四种可回收骨架:生物质、生物炭、工业副产品以及垃圾焚烧灰。此外,还深入阐述了具有可回收骨架的形式稳定 PCM 的应用范围。此外,还讨论了具有可回收骨架的形态稳定 PCMs 所面临的主要挑战,并提出了未来的研究趋势。本文对具有可回收骨架的形态稳定 PCMs 进行了系统综述,为进一步减少碳排放和促进可持续能源的发展提供了重要指导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Recent advances in energy storage and applications of form-stable phase change materials with recyclable skeleton

Recent advances in energy storage and applications of form-stable phase change materials with recyclable skeleton

With the expansion of the global population, the energy shortage is becoming increasingly acute. Phase change materials (PCMs) are considered green and efficient mediums for thermal energy storage, but the leakage problem caused by volume instability during phase change limits their application. Encapsulating PCMs with supporting materials can effectively avoid leakage, but most supporting materials are expensive and consume huge of natural resources. Carbon materials, which are rich and renewable resources, can be used as economical and environmentally friendly supporting skeletons to prepare form-stable PCMs. Although many researchers have begun to use recyclable materials especially various derivatives of carbon as supporting skeletons to prepare form-stable PCMs, the preparation methods, thermophysical properties and applications of form-stable PCMs with recyclable skeletons have rarely been systematically summarized yet. Form-stable PCMs with a recyclable skeleton can be used as green and efficient thermal storage materials due to their high heat storage capacity and good thermophysical stability after 2000 thermal cycles. This review investigates the effects of recyclable skeletons on the thermophysical properties including phase change temperature, latent heat, thermal conductivity, supercooling, and thermal cycling reliability. Four major kinds of recyclable skeletons are focused on: biomass, biochar, industrial by-products as well as waste incineration ash. Additionally, the application scales of form-stable PCMs with recyclable skeletons are explicated in depth. Moreover, the main challenges confronted by form-stable PCMs with recyclable skeletons are discussed, and future research trends are proposed. This article provides a systematic review of the form-stable PCMs with recyclable skeletons, giving significant guidance for further reducing carbon emissions and promoting the development of sustainable energy.

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