Designing the next generation of symmetrical organic redox flow batteries using helical carbocations

In recent years, non-aqueous fully organic Redox Flow Batteries (RFBs) have displayed potential in broadening the electrochemical window and enhancing energy density in RFBs by relying on redox-active organic molecules to provide improved sustainability in comparison to metal-based charge carriers. Of particular interest, systems that rely on a single bipolar redox molecule (BRM) for their operation, known as symmetrical organic RFBs, have gained momentum as the utilization of a BRM eliminates membrane crossover issues, thus extending the lifespan of electrical energy storage systems while reducing their cost. In this manuscript, we will present our contribution to this field through the design of tunable bipolar molecules within the helicene carbocation class. This particular type of BRM is synthetically very affordable and has proven to be highly modifiable and robust. Through the examination of 11 examples, we will demonstrate how an approach based on readily available electrochemical tools can be efficiently employed to generate and assess a library of compounds for future full flow RFB applications.