Laboratory reflectance spectra of enstatite and oldhamite mixtures for comparison with Earth-based reflectance spectra of asteroid 2867 Šteins and Mercury

The reflectance spectra of synthetic oldhamite (CaS), synthetic enstatite (Mg₂Si₂O₆), and their mixtures have been studied in the spectral range from 0.3 μm to 16 μm. The spectrum of enstatite is very bright, with a steep slope in the ultraviolet (UV) and an almost neutral slope in the visible (VIS) and near-infrared (NIR). The mid-infrared (MIR) region is characterized by the Christiansen feature, Reststrahlen bands and the Transparency feature. The oldhamite spectrum shows a red slope in the UV and VIS and an absorption band at 0.41 μm. The absorption band has a relative depth of 11.4%. In the MIR, the oldhamite spectrum is much brighter than the enstatite spectrum and shows several broad absorption bands. The spectra of the mixtures show an intermediate behavior between the two endmembers. The absorption band at 0.41 μm is visible in the spectra of all mixtures, even in the spectrum of the mixture with only 1 vol% oldhamite. In the MIR, the spectra of the mixtures with ≤10 vol% oldhamite are very similar to the spectrum of pure enstatite. Changes in the spectral characteristics such as reflectance or band depths do not follow simple linear trends but show two distinct trends: One for mixtures with ≤10 vol% oldhamite and one for mixtures with ≥20 vol% oldhamite. Changes occur significantly faster in the spectra of mixtures with ≤10 vol% than in those with ≥20 vol% oldhamite.

Reflectance spectra of the E[II]-type asteroid 2867 Šteins are flat and almost featureless but show an absorption band at 0.49 μm, which is attributed to oldhamite. Comparison of the laboratory spectra in the VIS and MIR with spectra of Šteins gives an upper limit for the oldhamite content on its surface of 40 %vol. Hence, Šteins probably consists of aubrite-like material with virtually FeO-free enstatite as the major constituent and an oldhamite abundance of <40 vol%. Šteins and other E[II]-type asteroids likely formed through igneous processes on a larger now destroyed body, where an immiscible CaS-melt formed within a silicate melt.

The surface of Mercury is also linked to FeO-poor silicates like enstatite. Oldhamite and other sulfides are linked to the formation of hollows on Mercury. Mixtures of enstatite and oldhamite could therefore serve as suitable model analog for the surface of Mercury. Contrasting trends at ∼7–8.5 μm in the MIR reflectance spectra of oldhamite and enstatite could be used as an indicator for the presence of oldhamite in spectral data that will be collected by the MERTIS (Mercury Radiometer and Thermal Infrared Spectrometer) instrument onboard the ESA/JAXA BepiColombo mission to Mercury.