{"title":"下寒武统页岩的初级生产、稀释和保存对有机质积累的影响","authors":"Jin Chai, Ruifei Wang, Sen Zheng","doi":"10.1007/s10553-024-01666-1","DOIUrl":null,"url":null,"abstract":"<p>In order to investigate the influence of primary production, dilution and preservation on organic matter accumulation, geochemical data and geochemical proxies of primary production, clastic influx and redox conditions were presented from the Cambrian Niutitang Formation organic-rich shales. The primary production proxies (TOC, Mo, P, Ba and Babio) and redox proxies (Ni/Co, V/Cr, U/Al and Th/U) suggest that the black organic-rich shales of the Niutitang Formation are deposited in anoxic/euxinic condition with high primary production. The pyrite of the Niutitang Formation is composed of spherical framboids, indicating that the anoxic bottom water could not prevail before organic matter degradation during the Niutitang Formation deposition. High primary production enhances organic carbon flux into chemocline layer and bottom water, leading to the anoxic bottom water from oxygen consumption by microorganisms and organic matter degradation. The anoxic bottom water in turn is beneficial to preservation of organic matter. In addition, Ti/Al ratios correlate well with TOC contents through the Niutitang Formation, indicating that clastic inputs enhance the burial rate for preventing organic matter from degradation during Niutitang Formation deposition. Therefore, the accumulation of organic matter in the Niutitang Formation is mainly influenced by primary production rather than the redox conditions in bottom water.</p>","PeriodicalId":9908,"journal":{"name":"Chemistry and Technology of Fuels and Oils","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Primary Production, Dilution and Preservation on Organic Matter Accumulation for the Lower Cambrian Shale\",\"authors\":\"Jin Chai, Ruifei Wang, Sen Zheng\",\"doi\":\"10.1007/s10553-024-01666-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In order to investigate the influence of primary production, dilution and preservation on organic matter accumulation, geochemical data and geochemical proxies of primary production, clastic influx and redox conditions were presented from the Cambrian Niutitang Formation organic-rich shales. The primary production proxies (TOC, Mo, P, Ba and Babio) and redox proxies (Ni/Co, V/Cr, U/Al and Th/U) suggest that the black organic-rich shales of the Niutitang Formation are deposited in anoxic/euxinic condition with high primary production. The pyrite of the Niutitang Formation is composed of spherical framboids, indicating that the anoxic bottom water could not prevail before organic matter degradation during the Niutitang Formation deposition. High primary production enhances organic carbon flux into chemocline layer and bottom water, leading to the anoxic bottom water from oxygen consumption by microorganisms and organic matter degradation. The anoxic bottom water in turn is beneficial to preservation of organic matter. In addition, Ti/Al ratios correlate well with TOC contents through the Niutitang Formation, indicating that clastic inputs enhance the burial rate for preventing organic matter from degradation during Niutitang Formation deposition. Therefore, the accumulation of organic matter in the Niutitang Formation is mainly influenced by primary production rather than the redox conditions in bottom water.</p>\",\"PeriodicalId\":9908,\"journal\":{\"name\":\"Chemistry and Technology of Fuels and Oils\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2024-03-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry and Technology of Fuels and Oils\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1007/s10553-024-01666-1\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry and Technology of Fuels and Oils","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1007/s10553-024-01666-1","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Effect of Primary Production, Dilution and Preservation on Organic Matter Accumulation for the Lower Cambrian Shale
In order to investigate the influence of primary production, dilution and preservation on organic matter accumulation, geochemical data and geochemical proxies of primary production, clastic influx and redox conditions were presented from the Cambrian Niutitang Formation organic-rich shales. The primary production proxies (TOC, Mo, P, Ba and Babio) and redox proxies (Ni/Co, V/Cr, U/Al and Th/U) suggest that the black organic-rich shales of the Niutitang Formation are deposited in anoxic/euxinic condition with high primary production. The pyrite of the Niutitang Formation is composed of spherical framboids, indicating that the anoxic bottom water could not prevail before organic matter degradation during the Niutitang Formation deposition. High primary production enhances organic carbon flux into chemocline layer and bottom water, leading to the anoxic bottom water from oxygen consumption by microorganisms and organic matter degradation. The anoxic bottom water in turn is beneficial to preservation of organic matter. In addition, Ti/Al ratios correlate well with TOC contents through the Niutitang Formation, indicating that clastic inputs enhance the burial rate for preventing organic matter from degradation during Niutitang Formation deposition. Therefore, the accumulation of organic matter in the Niutitang Formation is mainly influenced by primary production rather than the redox conditions in bottom water.
期刊介绍:
Chemistry and Technology of Fuels and Oils publishes reports on improvements in the processing of petroleum and natural gas and cracking and refining techniques for the production of high-quality fuels, oils, greases, specialty fluids, additives and synthetics. The journal includes timely articles on the demulsification, desalting, and desulfurizing of crude oil; new flow plans for refineries; platforming, isomerization, catalytic reforming, and alkylation processes for obtaining aromatic hydrocarbons and high-octane gasoline; methods of producing ethylene, acetylene, benzene, acids, alcohols, esters, and other compounds from petroleum, as well as hydrogen from natural gas and liquid products.