J. H. den Otter, M. C. Olde, W. van de Steeg, A. W. F. Volker, A. E. D. M. van der Heijden
{"title":"东斯海尔德河海弃弹药劣化研究","authors":"J. H. den Otter, M. C. Olde, W. van de Steeg, A. W. F. Volker, A. E. D. M. van der Heijden","doi":"10.1002/prep.202300302","DOIUrl":null,"url":null,"abstract":"Vast amounts of surplus ammunition were dumped in surface waters around the world. After degradation and corrosion of shells, both metal compounds and the energetic contents of the ammunition end up in the environment. These compounds or their metabolites are toxic to the environment and human health. Also in the Netherlands, ammunition was dumped over a period of several decades after World War II at several marine sites. One of these dumpsites is the Eastern Scheldt near Zierikzee. During the monitoring campaign of the ammunition dumpsite in the Eastern Scheldt in 2020, ammunition items were surfaced. The corrosion and presence of leak pathways of sea‐dumped munition were studied for a selection of munition items after being more than 50 years on the seabed in the Eastern Scheldt. For some of the items an estimated uniform corrosion rate of 0.01–0.03 mm/year was determined. Furthermore, a non‐destructive inspection technique based on an ultrasonic method was applied to measure the casing thickness profile. The obtained results corresponded well with the manually determined thickness profiles. The ultrasound method opens the possibility to measure the casing thickness of even intact munition items, thus avoiding the dissection of the munition item and removal of the explosive fill.","PeriodicalId":20800,"journal":{"name":"Propellants, Explosives, Pyrotechnics","volume":"85 1","pages":""},"PeriodicalIF":1.7000,"publicationDate":"2024-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Deterioration study of sea‐dumped munitions in the eastern Scheldt\",\"authors\":\"J. H. den Otter, M. C. Olde, W. van de Steeg, A. W. F. Volker, A. E. D. M. van der Heijden\",\"doi\":\"10.1002/prep.202300302\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Vast amounts of surplus ammunition were dumped in surface waters around the world. After degradation and corrosion of shells, both metal compounds and the energetic contents of the ammunition end up in the environment. These compounds or their metabolites are toxic to the environment and human health. Also in the Netherlands, ammunition was dumped over a period of several decades after World War II at several marine sites. One of these dumpsites is the Eastern Scheldt near Zierikzee. During the monitoring campaign of the ammunition dumpsite in the Eastern Scheldt in 2020, ammunition items were surfaced. The corrosion and presence of leak pathways of sea‐dumped munition were studied for a selection of munition items after being more than 50 years on the seabed in the Eastern Scheldt. For some of the items an estimated uniform corrosion rate of 0.01–0.03 mm/year was determined. Furthermore, a non‐destructive inspection technique based on an ultrasonic method was applied to measure the casing thickness profile. The obtained results corresponded well with the manually determined thickness profiles. The ultrasound method opens the possibility to measure the casing thickness of even intact munition items, thus avoiding the dissection of the munition item and removal of the explosive fill.\",\"PeriodicalId\":20800,\"journal\":{\"name\":\"Propellants, Explosives, Pyrotechnics\",\"volume\":\"85 1\",\"pages\":\"\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-03-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Propellants, Explosives, Pyrotechnics\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1002/prep.202300302\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Propellants, Explosives, Pyrotechnics","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/prep.202300302","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Deterioration study of sea‐dumped munitions in the eastern Scheldt
Vast amounts of surplus ammunition were dumped in surface waters around the world. After degradation and corrosion of shells, both metal compounds and the energetic contents of the ammunition end up in the environment. These compounds or their metabolites are toxic to the environment and human health. Also in the Netherlands, ammunition was dumped over a period of several decades after World War II at several marine sites. One of these dumpsites is the Eastern Scheldt near Zierikzee. During the monitoring campaign of the ammunition dumpsite in the Eastern Scheldt in 2020, ammunition items were surfaced. The corrosion and presence of leak pathways of sea‐dumped munition were studied for a selection of munition items after being more than 50 years on the seabed in the Eastern Scheldt. For some of the items an estimated uniform corrosion rate of 0.01–0.03 mm/year was determined. Furthermore, a non‐destructive inspection technique based on an ultrasonic method was applied to measure the casing thickness profile. The obtained results corresponded well with the manually determined thickness profiles. The ultrasound method opens the possibility to measure the casing thickness of even intact munition items, thus avoiding the dissection of the munition item and removal of the explosive fill.
期刊介绍:
Propellants, Explosives, Pyrotechnics (PEP) is an international, peer-reviewed journal containing Full Papers, Short Communications, critical Reviews, as well as details of forthcoming meetings and book reviews concerned with the research, development and production in relation to propellants, explosives, and pyrotechnics for all applications. Being the official journal of the International Pyrotechnics Society, PEP is a vital medium and the state-of-the-art forum for the exchange of science and technology in energetic materials. PEP is published 12 times a year.
PEP is devoted to advancing the science, technology and engineering elements in the storage and manipulation of chemical energy, specifically in propellants, explosives and pyrotechnics. Articles should provide scientific context, articulate impact, and be generally applicable to the energetic materials and wider scientific community. PEP is not a defense journal and does not feature the weaponization of materials and related systems or include information that would aid in the development or utilization of improvised explosive systems, e.g., synthesis routes to terrorist explosives.