具有不同烷基链长度的卟啉铁(III)氯化物的液晶行为

IF 0.9 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Journal of Porphyrins and Phthalocyanines Pub Date : 2024-02-15 DOI:10.1142/s1088424624500032

Dumrongsak Aryuwananon, Suttinun Phongtamrug, Buncha Pulpoka

{"title":"具有不同烷基链长度的卟啉铁(III)氯化物的液晶行为","authors":"Dumrongsak Aryuwananon, Suttinun Phongtamrug, Buncha Pulpoka","doi":"10.1142/s1088424624500032","DOIUrl":null,"url":null,"abstract":"Two novel porphyrin liquid crystals were designed and synthesized. Their structures were characterized by NMR, FT-IR, UV-visible, and mass spectroscopies. The liquid crystalline properties were investigated by DSC, POM and XRD analyses. The C<math altimg=\"eq-00001.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mn>1</mn><mn>2</mn></mrow></msub></math> and C<math altimg=\"eq-00002.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mn>1</mn><mn>8</mn></mrow></msub></math> alkyl chains porphyrin iron(III) complex (1-2) displayed three liquid crystalline transitions in a wide temperature range. Both long alkyl chain porphyrin iron(III) complexes were exhibited a columnar mesophase type.","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"32 1","pages":""},"PeriodicalIF":0.9000,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Liquid crystalline behaviors of porphyrin iron(III) chloride complexes with different alkyl chain lengths\",\"authors\":\"Dumrongsak Aryuwananon, Suttinun Phongtamrug, Buncha Pulpoka\",\"doi\":\"10.1142/s1088424624500032\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Two novel porphyrin liquid crystals were designed and synthesized. Their structures were characterized by NMR, FT-IR, UV-visible, and mass spectroscopies. The liquid crystalline properties were investigated by DSC, POM and XRD analyses. The C<math altimg=\\\"eq-00001.gif\\\" display=\\\"inline\\\" overflow=\\\"scroll\\\"><msub><mrow></mrow><mrow><mn>1</mn><mn>2</mn></mrow></msub></math> and C<math altimg=\\\"eq-00002.gif\\\" display=\\\"inline\\\" overflow=\\\"scroll\\\"><msub><mrow></mrow><mrow><mn>1</mn><mn>8</mn></mrow></msub></math> alkyl chains porphyrin iron(III) complex (1-2) displayed three liquid crystalline transitions in a wide temperature range. Both long alkyl chain porphyrin iron(III) complexes were exhibited a columnar mesophase type.\",\"PeriodicalId\":16876,\"journal\":{\"name\":\"Journal of Porphyrins and Phthalocyanines\",\"volume\":\"32 1\",\"pages\":\"\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-02-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Porphyrins and Phthalocyanines\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1142/s1088424624500032\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Porphyrins and Phthalocyanines","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1142/s1088424624500032","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

设计并合成了两种新型卟啉液晶。通过核磁共振、傅立叶变换红外光谱、紫外-可见光谱和质谱对它们的结构进行了表征。通过 DSC、POM 和 XRD 分析研究了它们的液晶特性。C12 和 C18 烷基链卟啉铁(III)络合物（1-2）在很宽的温度范围内显示出三种液晶转变。两种长烷基链卟啉铁(III)络合物都呈现出柱状介相类型。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Liquid crystalline behaviors of porphyrin iron(III) chloride complexes with different alkyl chain lengths

Two novel porphyrin liquid crystals were designed and synthesized. Their structures were characterized by NMR, FT-IR, UV-visible, and mass spectroscopies. The liquid crystalline properties were investigated by DSC, POM and XRD analyses. The C $_{12}$ and C $_{18}$ alkyl chains porphyrin iron(III) complex (1-2) displayed three liquid crystalline transitions in a wide temperature range. Both long alkyl chain porphyrin iron(III) complexes were exhibited a columnar mesophase type.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Porphyrins and Phthalocyanines 化学-化学综合

CiteScore

2.10

自引率

20.00%

发文量

审稿时长

1 months

期刊介绍： The Journal of Porphyrins and Phthalocyanines (JPP) covers research in the chemistry, physics, biology and technology of porphyrins, phthalocyanines and related macrocycles. Research papers, review articles and short communications deal with the synthesis, spectroscopy, processing and applications of these compounds.