Yan Wang, Wei Wei Cheng, Yi Mou, Shuai Wen, Dongkai Wang, Yun Shan Xue
{"title":"用于高灵敏度检测水介质中硝基呋喃妥因的双重互穿二维锌（II）配位聚合物。","authors":"Yan Wang, Wei Wei Cheng, Yi Mou, Shuai Wen, Dongkai Wang, Yun Shan Xue","doi":"10.1107/S2053229624002171","DOIUrl":null,"url":null,"abstract":"<p><p>A novel Zn<sup>II</sup> coordination polymer, namely, poly[{μ<sub>2</sub>-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl]methanone-κ<sup>2</sup>N<sup>3</sup>:N<sup>3'</sup>}(μ<sub>2</sub>-5-bromobenzene-1,3-dicarboxylato-κ<sup>2</sup>O<sup>1</sup>:O<sup>3</sup>)zinc(II)], [Zn(C<sub>8</sub>H<sub>3</sub>BrO<sub>4</sub>)(C<sub>21</sub>H<sub>18</sub>N<sub>4</sub>O)]<sub>n</sub> or [Zn(Br-BDC)(MIPMO)]<sub>n</sub>, (I), has been synthesized by the solvothermal method using 5-bromoisophthalic acid (Br-H<sub>2</sub>BDC), bis[4-(2-methyl-1H-imidazol-1-yl)phenyl]methanone (MIPMO) and Zn(NO<sub>3</sub>)<sub>2</sub>·6H<sub>2</sub>O. Structure analysis showed that compound (I) displays twofold parallel interwoven sql nets. Fluorescence experiments confirmed that the compound can sensitively and selectively detect nitrofurantoin (NFT) in aqueous medium. In addition, the possible fluorescence quenching mechanisms of compound (I) toward NFT are investigated.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":" ","pages":"98-103"},"PeriodicalIF":0.7000,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A twofold interpenetrated two-dimensional zinc(II) coordination polymer for the highly sensitive detection of nitrofurantoin in aqueous medium.\",\"authors\":\"Yan Wang, Wei Wei Cheng, Yi Mou, Shuai Wen, Dongkai Wang, Yun Shan Xue\",\"doi\":\"10.1107/S2053229624002171\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>A novel Zn<sup>II</sup> coordination polymer, namely, poly[{μ<sub>2</sub>-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl]methanone-κ<sup>2</sup>N<sup>3</sup>:N<sup>3'</sup>}(μ<sub>2</sub>-5-bromobenzene-1,3-dicarboxylato-κ<sup>2</sup>O<sup>1</sup>:O<sup>3</sup>)zinc(II)], [Zn(C<sub>8</sub>H<sub>3</sub>BrO<sub>4</sub>)(C<sub>21</sub>H<sub>18</sub>N<sub>4</sub>O)]<sub>n</sub> or [Zn(Br-BDC)(MIPMO)]<sub>n</sub>, (I), has been synthesized by the solvothermal method using 5-bromoisophthalic acid (Br-H<sub>2</sub>BDC), bis[4-(2-methyl-1H-imidazol-1-yl)phenyl]methanone (MIPMO) and Zn(NO<sub>3</sub>)<sub>2</sub>·6H<sub>2</sub>O. Structure analysis showed that compound (I) displays twofold parallel interwoven sql nets. Fluorescence experiments confirmed that the compound can sensitively and selectively detect nitrofurantoin (NFT) in aqueous medium. In addition, the possible fluorescence quenching mechanisms of compound (I) toward NFT are investigated.</p>\",\"PeriodicalId\":7115,\"journal\":{\"name\":\"Acta Crystallographica Section C Structural Chemistry\",\"volume\":\" \",\"pages\":\"98-103\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2024-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Crystallographica Section C Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1107/S2053229624002171\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/3/12 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Crystallographica Section C Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1107/S2053229624002171","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/3/12 0:00:00","PubModel":"Epub","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A twofold interpenetrated two-dimensional zinc(II) coordination polymer for the highly sensitive detection of nitrofurantoin in aqueous medium.
A novel ZnII coordination polymer, namely, poly[{μ2-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl]methanone-κ2N3:N3'}(μ2-5-bromobenzene-1,3-dicarboxylato-κ2O1:O3)zinc(II)], [Zn(C8H3BrO4)(C21H18N4O)]n or [Zn(Br-BDC)(MIPMO)]n, (I), has been synthesized by the solvothermal method using 5-bromoisophthalic acid (Br-H2BDC), bis[4-(2-methyl-1H-imidazol-1-yl)phenyl]methanone (MIPMO) and Zn(NO3)2·6H2O. Structure analysis showed that compound (I) displays twofold parallel interwoven sql nets. Fluorescence experiments confirmed that the compound can sensitively and selectively detect nitrofurantoin (NFT) in aqueous medium. In addition, the possible fluorescence quenching mechanisms of compound (I) toward NFT are investigated.
期刊介绍：
Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.
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