Yang Zhang , Qizhuang Zou , Ruiqi Fang , Hua Tan , Hongbing Ji , Yingwei Li
{"title":"用于高效糠醛缩醛化的 MOF 衍生 Fe3O4@SiO2/Al2O3 卵黄壳纳米反应器","authors":"Yang Zhang , Qizhuang Zou , Ruiqi Fang , Hua Tan , Hongbing Ji , Yingwei Li","doi":"10.1016/j.catcom.2024.106900","DOIUrl":null,"url":null,"abstract":"<div><p>Yolk-shell nanoreactors feature numbers of advantages in promoting catalytic performance. This work demonstrates the fabrication of yolk-shell Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub>-<em>T</em> (<em>T</em> = 500–900 °C) from metal-organic framework. Characterizations indicate the Fe<sub>3</sub>O<sub>4</sub> yolk and SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> shell of the obtained nanoreactors. Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub>–800 showed excellent performance in furfural acetalization to 2-(dimethoxymethyl)furan, achieving a 97% yield at 60 °C, atmospheric pressure within 5 h. Control experiments reveal the high reactivity of Fe<sub>3</sub>O<sub>4</sub> yolks for furfural acetalization, and acidic Al species are favorable for reactivity promotion. Besides, porous SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> shells facilitate mass transfer and increase the accessibility of active sites, also contribute to the high performance and stability.</p></div>","PeriodicalId":263,"journal":{"name":"Catalysis Communications","volume":"187 ","pages":"Article 106900"},"PeriodicalIF":3.4000,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1566736724000608/pdfft?md5=8f3a0608813be26deef6ff1bbb727283&pid=1-s2.0-S1566736724000608-main.pdf","citationCount":"0","resultStr":"{\"title\":\"MOF-derived Fe3O4@SiO2/Al2O3 yolk-shell nanoreactor for efficient furfural acetalization\",\"authors\":\"Yang Zhang , Qizhuang Zou , Ruiqi Fang , Hua Tan , Hongbing Ji , Yingwei Li\",\"doi\":\"10.1016/j.catcom.2024.106900\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Yolk-shell nanoreactors feature numbers of advantages in promoting catalytic performance. This work demonstrates the fabrication of yolk-shell Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub>-<em>T</em> (<em>T</em> = 500–900 °C) from metal-organic framework. Characterizations indicate the Fe<sub>3</sub>O<sub>4</sub> yolk and SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> shell of the obtained nanoreactors. Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub>–800 showed excellent performance in furfural acetalization to 2-(dimethoxymethyl)furan, achieving a 97% yield at 60 °C, atmospheric pressure within 5 h. Control experiments reveal the high reactivity of Fe<sub>3</sub>O<sub>4</sub> yolks for furfural acetalization, and acidic Al species are favorable for reactivity promotion. Besides, porous SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> shells facilitate mass transfer and increase the accessibility of active sites, also contribute to the high performance and stability.</p></div>\",\"PeriodicalId\":263,\"journal\":{\"name\":\"Catalysis Communications\",\"volume\":\"187 \",\"pages\":\"Article 106900\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2024-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1566736724000608/pdfft?md5=8f3a0608813be26deef6ff1bbb727283&pid=1-s2.0-S1566736724000608-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1566736724000608\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1566736724000608","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
MOF-derived Fe3O4@SiO2/Al2O3 yolk-shell nanoreactor for efficient furfural acetalization
Yolk-shell nanoreactors feature numbers of advantages in promoting catalytic performance. This work demonstrates the fabrication of yolk-shell Fe3O4@SiO2/Al2O3-T (T = 500–900 °C) from metal-organic framework. Characterizations indicate the Fe3O4 yolk and SiO2/Al2O3 shell of the obtained nanoreactors. Fe3O4@SiO2/Al2O3–800 showed excellent performance in furfural acetalization to 2-(dimethoxymethyl)furan, achieving a 97% yield at 60 °C, atmospheric pressure within 5 h. Control experiments reveal the high reactivity of Fe3O4 yolks for furfural acetalization, and acidic Al species are favorable for reactivity promotion. Besides, porous SiO2/Al2O3 shells facilitate mass transfer and increase the accessibility of active sites, also contribute to the high performance and stability.
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Catalysis Communications aims to provide rapid publication of significant, novel, and timely research results homogeneous, heterogeneous, and enzymatic catalysis.
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