制备掺杂氧化锡的氟化氧化锆纳米复合材料,用于光催化降解受污染水体中的有机染料

Vanasundari Karuppaiya, Viji Arangarajan, Vijayakumar Rajendran, Ikhyun Kim, Imran Hasan, Sivaprakash Paramasivam
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摘要

本研究通过温和的化学反应成功合成了一种新型 SnO2-Zr-F 纳米结构复合材料。利用 XRD 对该复合材料的结晶性质进行了表征,发现其平均结晶尺寸为 28.31 nm。FE-SEM 图像显示了具有适当元素比例的团聚球形形态。该纳米复合材料的光学特性可通过紫外-可见光谱和陶氏图确定,计算得出的带隙为 2 eV。在日光下 150 分钟,对阳离子(罗丹明 B)和阴离子(曙红黄)染料的光催化活性进行了评估,结果表明最大降解效率分别为 92% 和 98%。此外,还评估了复合材料对金黄色葡萄球菌和大肠杆菌的抗菌性能。研究结果表明,所制备的纳米复合材料在光催化和抗菌领域都具有很好的功效,在环境应用方面具有广阔的发展前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation of fluorinated zirconia doped with tin oxide nanocomposites for photocatalytic degradation of organic dyes in contaminated water bodies
In this study, a novel SnO2–Zr–F nanostructured composite was successfully synthesized through a mild chemical reaction. The crystalline nature of the composite was characterized using XRD, revealing an average crystalline size of 28.31 nm. FE-SEM images illustrated an agglomerated spherical morphology with appropriate elemental ratios. The optical properties of the nanocomposite are identified by UV–vis spectroscopy with Tauc plot, and the calculated bandgap is 2 eV. Photocatalytic activity was assessed against cationic (Rhodamine B) and anionic (Eosin yellow) dyes under sunlight for 150 min, resulting in a maximum degradation efficiency of 92 % and 98 %, respectively. Furthermore, the antibacterial performance of the composite was evaluated against S. aureus and E. coli bacteria. The findings suggest that the prepared nanocomposite exhibits promising potential for environmental applications, showcasing its efficacy in both photocatalytic and antibacterial domains.
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