未成功合成单个 1,1-二硝基乙烯

Jowita Kras, Maria Mikulska, Radwan Allnajar, Karolina Kula
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引用次数: 0

摘要

根据之前对其他 1-R-1-硝基乙烯实例所描述的程序,对制备游离的 1,1-二硝基乙烯的可能性进行了实验研究。结果发现,由于 1,1-二硝基乙烯的高反应性以及分解和低聚物化的倾向,这些方法无法用于制备标题化合物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Unsuccessful synthesis of individual 1,1-dinitroethene
The possibility of the preparation of free 1,1-dinitroethene was examined experimentally on the basis of procedures described earlier for other examples of 1-R-1-nitroethenes. It was found, that these types of protocols are non-usable for the preparation of the title compound due to its high reactivity and tendency to decomposition and oligomerization.
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