阿托品（2-苯基喹啉-4-羧酸）的新型衍生物

Q4 Chemistry

Proceedings of the National Academy of Sciences of Belarus, Chemical Series Pub Date : 2024-03-04 DOI:10.29235/1561-8331-2024-60-1-27-35

E. Dikusar, E. A. Akishina, S. Stepin, L. N. Filippovich, N. V. Bogdanova, S. N. Shahab, V. Potkin

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引用次数: 0

摘要

在二氯甲烷中，在三乙胺的存在下，用阿托品酰基盐酸盐对取代的羟基苯甲醛进行酰化，得到的酯与胺类（4-氨基偶氮苯、4-氨基安替比林）在甲醇中缩合时，能够形成 (E)- 氮甲基。此外，还获得了阿托芬烷与姜黄素天然片段的酯。研究发现，基于（E）-偶氮甲烷与偶氮苯片段的薄膜具有很强的偏振能力。

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Novel derivatives of atophan (2-phenylquinoline-4-carboxic acid)

Acylation of substituted hydroxybenzaldehydes with hydrochloride of atophane acylchloride in dichloromethane in the presence of triethylamine gave esters, capable of forming (E)-azomethines when condensed with amines (4-aminoazobenzene, 4-aminoantipyrine) in methanol. In addition, an ester of atophane with a natural fragment of curcumin was obtained. Films based on (E)-azomethine with an azobenzene fragment were found to have a high polarizing ability.

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来源期刊

Proceedings of the National Academy of Sciences of Belarus, Chemical Series Chemistry-Chemistry (miscellaneous)

CiteScore

0.30

自引率

0.00%

发文量