5-溴-2-(苯基氨基)苯甲酸

IUCrData Pub Date : 2024-03-01 DOI:10.1107/S2414314624001986

Liping Kang , Sihui Long , W. T. A. Harrison (Editor)

{"title":"5-溴-2-(苯基氨基)苯甲酸","authors":"Liping Kang , Sihui Long , W. T. A. Harrison (Editor)","doi":"10.1107/S2414314624001986","DOIUrl":null,"url":null,"abstract":"<div>The molecules of the title compound pair up to form carboxylic acid–carboxylic acid homodimers in the crystal structure.</div><div>The title compound, C13H10BrNO2, was obtained by the reaction of 2,5-dibromobenzoic acid and aniline. The molecule is twisted with a dihedral angle between the aromatic rings of 45.74 (11)° and an intramolecular N—H⋯O hydrogen bond is seen. In the crystal, pairwise O—H⋯O hydrogen bonds generate carboxylic acid inversion dimers. <figure><img><ol><li>Download : Download high-res image (220KB)</li><li>Download : Download full-size image</li></ol></figure> </div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"5-Bromo-2-(phenylamino)benzoic acid\",\"authors\":\"Liping Kang , Sihui Long , W. T. A. Harrison (Editor)\",\"doi\":\"10.1107/S2414314624001986\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>The molecules of the title compound pair up to form carboxylic acid–carboxylic acid homodimers in the crystal structure.</div><div>The title compound, C13H10BrNO2, was obtained by the reaction of 2,5-dibromobenzoic acid and aniline. The molecule is twisted with a dihedral angle between the aromatic rings of 45.74 (11)° and an intramolecular N—H⋯O hydrogen bond is seen. In the crystal, pairwise O—H⋯O hydrogen bonds generate carboxylic acid inversion dimers. <figure><img><ol><li>Download : Download high-res image (220KB)</li><li>Download : Download full-size image</li></ol></figure> </div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000099\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000099","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

标题化合物 C13H10BrNO2 是由 2,5-二溴苯甲酸和苯胺反应得到的。分子呈扭曲状，芳香环之间的二面角为 45.74 (11)°，并出现分子内 N-H...O 氢键。在晶体中，成对的 O-H...O 氢键产生羧酸反转二聚体。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

5-Bromo-2-(phenylamino)benzoic acid

The molecules of the title compound pair up to form carboxylic acid–carboxylic acid homodimers in the crystal structure.

The title compound, C₁₃H₁₀BrNO₂, was obtained by the reaction of 2,5-dibromobenzoic acid and aniline. The molecule is twisted with a dihedral angle between the aromatic rings of 45.74 (11)° and an intramolecular N—H⋯O hydrogen bond is seen. In the crystal, pairwise O—H⋯O hydrogen bonds generate carboxylic acid inversion dimers.

Download : Download high-res image (220KB)
Download : Download full-size image

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

IUCrData

CiteScore

0.30

自引率

0.00%

发文量