新的高能 1,2,4-三唑-硝基呋喃杂化物

IF 2 3区化学 Q2 CHEMISTRY, ORGANIC

Journal of Heterocyclic Chemistry Pub Date : 2024-03-05 DOI:10.1002/jhet.4797

Alexander A. Larin, Ekaterina V. Dubasova, Ivan V. Ananyev, Konstantin A. Monogarov, Galina A. Gazieva, Leonid L. Fershtat

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引用次数: 0

摘要

我们合理地设计和合成了由 1,2,4- 三唑和呋喃环组成并带有易爆硝基的新型高能材料。对所有新制备的化合物进行了全面的表征和理化性质评估。在新合成的系列中，(1,2,4-三唑基)呋喃 4 对冲击和摩擦完全不敏感，并具有良好的引爆性能（D = 8.4 km s-1; P = 33 GPa），使其能够作为一种有前途的高能材料得到进一步的探索。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

New energetic 1,2,4-triazole-nitrofuroxan hybrids

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New energetic 1,2,4-triazole-nitrofuroxan hybrids

New promising energetic materials comprised of 1,2,4-triazole and furoxan rings and bearing explosophoric nitro group were rationally designed and synthesized. All newly prepared compounds were thoroughly characterized and their physicochemical properties were estimated. In the newly synthesized series, (1,2,4-triazolyl)furoxan 4 is completely insensitive to impact and friction and possesses good detonation performance (D = 8.4 km s⁻¹; P = 33 GPa) enabling its further exploration as a promising high-energy material.

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来源期刊

Journal of Heterocyclic Chemistry 化学-有机化学

CiteScore

5.20

自引率

4.20%

发文量

177

审稿时长

3.9 months

期刊介绍： The Journal of Heterocyclic Chemistry is interested in publishing research on all aspects of heterocyclic chemistry, especially development and application of efficient synthetic methodologies and strategies for the synthesis of various heterocyclic compounds. In addition, Journal of Heterocyclic Chemistry promotes research in other areas that contribute to heterocyclic synthesis/application, such as synthesis design, reaction techniques, flow chemistry and continuous processing, multiphase catalysis, green chemistry, catalyst immobilization and recycling.