C2+ 碳氢化合物/H2 混合物的非催化部分氧化作用

IF 1.3 4区 工程技术 Q3 CHEMISTRY, ORGANIC
V. I. Savchenko, A. V. Ozerskii, A. V. Nikitin, I. V. Sedov, V. S. Arutyunov
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引用次数: 0

摘要

本文报告了在 1400-1700 K 条件下对甲烷和 C2-C4 碳氢化合物/氢混合物(C/H = 1:4)进行非催化部分氧化的动力学和热力学分析结果。C2+ 碳氢化合物氧化转化的初始阶段包括热解,主要是分解成乙烯和丙烯,然后是热解产物的氧化。在这方面,C2+碳氢化合物氧化转化的动力学与甲烷转化的动力学不同,其特点是热解和氧化几乎同时发生,而且速度明显较慢。随后的阶段涉及氧化产物(即乙炔和甲烷)的蒸汽重整和干重整;这些阶段一直持续到主要产物(H2、CO、CO2 和 H2O)在给定温度下达到平衡分布为止。研究结果对于优化通过 C2+ 碳氢化合物部分氧化生产高温合成气的各种技术以及中度或高强度低氧稀释(MILD)燃烧过程非常重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Non-Catalytic Partial Oxidation of C2+ Hydrocarbon/H2 Mixtures

Non-Catalytic Partial Oxidation of C2+ Hydrocarbon/H2 Mixtures

Non-Catalytic Partial Oxidation of C2+ Hydrocarbon/H2 Mixtures

The paper reports the results of a kinetic and thermodynamic analysis of non-catalytic partial oxidation of methane and C2–C4 hydrocarbon/hydrogen mixtures (C/H = 1 : 4) at 1400–1700 K. The hydrocarbon conversion sequence and the time periods of the major process stages were identified for isothermal conditions. The initial stage of the oxidative conversion of C2+ hydrocarbons consists of their pyrolysis, primarily into ethylene and propylene, followed by oxidation of the pyrolysis products. In this respect, the kinetics of C2+ hydrocarbon oxidative conversion are different from those of methane conversion, marked by the almost simultaneous and significantly slower occurrence of pyrolysis and oxidation. The subsequent stages involve steam and dry reforming of the oxidation products, namely acetylene and methane; these stages continue until the main products (H2, CO, CO2, and H2O) reach an equilibrium distribution for the given temperature. The study findings are important for the optimization of various techniques for high-temperature syngas production via partial oxidation of C2+ hydrocarbons, as well as Moderate or Intense Low-Oxygen Dilution (MILD) combustion processes.

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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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