Jinfei Lu , Shaohua Wang , Yanheng Hao , Lu Lin , Fan Bai , Wenhao Cui , Juan Wang , Qingda An , Peng Tian , Jifeng Pang , Wenhao Luo
{"title":"粘合剂选择对生物质催化用沸石基双功能催化剂催化性能的影响","authors":"Jinfei Lu , Shaohua Wang , Yanheng Hao , Lu Lin , Fan Bai , Wenhao Cui , Juan Wang , Qingda An , Peng Tian , Jifeng Pang , Wenhao Luo","doi":"10.1016/j.catcom.2024.106892","DOIUrl":null,"url":null,"abstract":"<div><p>The impact of binder selection on catalytic performance of real catalyst extrudates is still limitedly shown in biomass catalysis. Herein, we have prepared two zeolite-based bifunctional extrudates (Ni/LaY-Al<sub>2</sub>O<sub>3</sub> and Ni/LaY-SiO<sub>2</sub>). Compared with Ni/LaY-Al<sub>2</sub>O<sub>3</sub>, Ni/LaY-SiO<sub>2</sub> shows a markedly enhanced durability and sustained performance for 936 h in the continuous liquid-phase hydrogenation of γ-valerolactone into methyl pentanoate. Complementary characterization studies reveal that choosing SiO<sub>2</sub> as binder could efficiently mitigate metal agglomeration, coke formation and support dealumination during catalysis. These findings showcase that binder selection is essential for catalyst durability in the development of the industrial-level bifunctional catalysts for biomass valorization.</p></div>","PeriodicalId":263,"journal":{"name":"Catalysis Communications","volume":"187 ","pages":"Article 106892"},"PeriodicalIF":3.4000,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1566736724000529/pdfft?md5=11700240203d5ad1c3def2381ec4ba18&pid=1-s2.0-S1566736724000529-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Influence of binder selection on the catalytic performance of zeolite-based bifunctional catalysts for biomass catalysis\",\"authors\":\"Jinfei Lu , Shaohua Wang , Yanheng Hao , Lu Lin , Fan Bai , Wenhao Cui , Juan Wang , Qingda An , Peng Tian , Jifeng Pang , Wenhao Luo\",\"doi\":\"10.1016/j.catcom.2024.106892\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The impact of binder selection on catalytic performance of real catalyst extrudates is still limitedly shown in biomass catalysis. Herein, we have prepared two zeolite-based bifunctional extrudates (Ni/LaY-Al<sub>2</sub>O<sub>3</sub> and Ni/LaY-SiO<sub>2</sub>). Compared with Ni/LaY-Al<sub>2</sub>O<sub>3</sub>, Ni/LaY-SiO<sub>2</sub> shows a markedly enhanced durability and sustained performance for 936 h in the continuous liquid-phase hydrogenation of γ-valerolactone into methyl pentanoate. Complementary characterization studies reveal that choosing SiO<sub>2</sub> as binder could efficiently mitigate metal agglomeration, coke formation and support dealumination during catalysis. These findings showcase that binder selection is essential for catalyst durability in the development of the industrial-level bifunctional catalysts for biomass valorization.</p></div>\",\"PeriodicalId\":263,\"journal\":{\"name\":\"Catalysis Communications\",\"volume\":\"187 \",\"pages\":\"Article 106892\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2024-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1566736724000529/pdfft?md5=11700240203d5ad1c3def2381ec4ba18&pid=1-s2.0-S1566736724000529-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1566736724000529\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1566736724000529","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Influence of binder selection on the catalytic performance of zeolite-based bifunctional catalysts for biomass catalysis
The impact of binder selection on catalytic performance of real catalyst extrudates is still limitedly shown in biomass catalysis. Herein, we have prepared two zeolite-based bifunctional extrudates (Ni/LaY-Al2O3 and Ni/LaY-SiO2). Compared with Ni/LaY-Al2O3, Ni/LaY-SiO2 shows a markedly enhanced durability and sustained performance for 936 h in the continuous liquid-phase hydrogenation of γ-valerolactone into methyl pentanoate. Complementary characterization studies reveal that choosing SiO2 as binder could efficiently mitigate metal agglomeration, coke formation and support dealumination during catalysis. These findings showcase that binder selection is essential for catalyst durability in the development of the industrial-level bifunctional catalysts for biomass valorization.
期刊介绍：
Catalysis Communications aims to provide rapid publication of significant, novel, and timely research results homogeneous, heterogeneous, and enzymatic catalysis.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
