采用自蔓延低温合成法生产纯碳化硅

IF 0.4 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS
V. M. Sizyakov, V. Yu. Bazhin, V. Yu. Piirainen, F. Yu. Sharikov, O. N. Mas’ko
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引用次数: 0

摘要

介绍了通过自传播合成法形成超纯碳化硅的研究成果。这种合成方法缩短了工艺时间,降低了能源成本。研究证实,主要的结构转变是由二氧化硅内部的相变和多晶现象(α-SiO2 向 β-SiO2 的转变)引起的,这是生产纯碳化硅所必需的。据测定,在一定的时间间隔内,在强加条件的影响下,以及随后与硅酸和活性碳的相互作用下,自发转变开始形成超纯碳化硅。采用该技术可将碳化硅的产量提高到 95 - 99%,纳米级产品(40 - 60 纳米)的纯度为 99.99%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Implemention of Self-Propagating Low-Temperature Synthesis to Produce Pure Silicon Carbide

Implemention of Self-Propagating Low-Temperature Synthesis to Produce Pure Silicon Carbide

Results of research into formation of ultrapure silicon carbide by self propagating synthesis are described. This synthesis provides a reduction in process time and energy costs. It is established that the main structural transition is caused by phase transformations and polymorphism phenomenon within silica (α-SiO2 to β-SiO2 transition) which is necessary to produce pure silicon carbide. It is determined that in a given time interval under the influence of imposed conditions and subsequent interaction with silicic acid and active carbon spontaneous transition begins with formation of ultrapure silicon carbide. Implementation of the proposed technology increases silicon carbide yield to 95 – 99% with a nanoscale product (40 – 60 nm) of 99.99% purity.

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来源期刊
Refractories and Industrial Ceramics
Refractories and Industrial Ceramics 工程技术-材料科学:硅酸盐
CiteScore
0.90
自引率
20.00%
发文量
38
审稿时长
6-12 weeks
期刊介绍: Refractories and Industrial Ceramics publishes peer-reviewed articles on the latest developments and discoveries in the field of refractory materials and ceramics, focusing on the practical aspects of their production and use. Topics covered include: Scientific Research; Raw Materials; Production; Equipment; Heat Engineering; Applications.
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