分子光化学分解形成的自由基中的电子-核排列

IF 0.9 4区化学 Q4 CHEMISTRY, PHYSICAL

High Energy Chemistry Pub Date : 2024-02-27 DOI:10.1134/s001814392309014x

P. A. Purtov

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引用次数: 0

摘要

摘要对分子光化学分解后形成的自由基中的电子-核排列（CIDEP 多重效应）进行了计算。自由基中的自旋相互排序：自由基中的电子自旋和核自旋平行或反平行。在运动学方法的框架内计算了弱磁场中自由基静止状态的种群。

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Electron–Nuclear Alignment in Radicals Formed by Photochemical Decomposition of Molecules

Abstract

Calculations of electron–nuclear alignment (CIDEP multiplet effect) in radicals formed as a result of the photochemical decomposition of molecules have been performed. There is a mutual ordering of spins in the radicals: the electron and nuclear spins in the radical are oriented parallel or antiparallel. The populations of stationary states of radicals in weak magnetic fields have been calculated in the framework of the kinematic approach.

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来源期刊

High Energy Chemistry 化学-物理化学

CiteScore

1.50

自引率

28.60%

发文量

审稿时长

6-12 weeks

期刊介绍： High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.