化学处理和伽马射线辐照对秋葵麻布增强高密度聚乙烯复合材料的影响

Mohammed Hossan Shahid Shohrawardy, Md Forhad Mina, AKM Moshiul Alam, Ruhul Amin Khan
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引用次数: 0

摘要

使用原纤维和碱处理纤维制备了秋葵麻布增强高密度聚乙烯(HDPE)热塑性复合材料,并对其进行了表征。对未加工的 Okra 热塑性复合材料和碱处理的 Okra 热塑性复合材料的纤维含量进行了优化,纤维含量的最佳值为 55 wt%。经过碱处理且纤维含量为 55 wt% 的样品随后暴露于剂量为 2.5、5 和 7.5 kGy 的伽马辐射中。只有受到 5 kGy 辐射的样品性能有所改善。通过 X 射线衍射分析观察到,经过处理的复合材料比未经处理的样品具有更高的结晶度。经 5 kGy 伽马射线照射的复合材料的断裂面显微照片显示出比其他样品更紧密的结构。通过对复合材料进行傅立叶变换红外光谱分析,发现 5 kGy 剂量的样品显示出 Okra 纤维与高密度聚乙烯基体之间的交联增强。与碱处理样品相比,辐照复合材料的吸水率更低。经过 5 kGy 伽马射线辐照的复合材料的拉伸强度和杨氏模量分别提高了 66 兆帕和 1925 兆帕。与未加工的复合材料和经过处理的复合材料相比,辐照剂量为 5 kGy 的复合材料在结构、机械和热性能方面都有所改善。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The impact of chemical treatment and gamma-ray irradiation on the okra hessian cloth reinforced high-density polyethylene composites
Okra hessian cloth-reinforced high-density polyethylene (HDPE) thermoplastic composites were prepared and characterized with both raw and alkali-treated fibers. The fiber contents were optimized for both the raw Okra thermoplastic composites and the alkali-treated Okra thermoplastic composites, and the optimum value of fiber content was 55 wt%. Samples that were alkali-treated and had 55 wt% fibers were subsequently exposed to gamma radiation at doses of 2.5, 5, and 7.5 kGy. Only the sample subjected to 5 kGy showed improved performance. Treated composites exhibited higher crystallinities than the untreated samples as observed by X-Ray diffraction analysis. The rupture surface micrographs of the composites exposed to 5 kGy gamma radiation revealed more compact than others. By using Fourier transform infrared spectroscopy analysis of composites, it was found that 5 kGy dose sample showed enhanced cross-linking between Okra fibers and HDPE matrix. The irradiated composite showed less water intake than the alkali-treated samples. Composites subjected to 5 kGy gamma rays showed improved tensile strength and Young’s modulus of values 66 MPa and 1925 MPa, respectively. Compared to raw and treated composites, the irradiated composites with a radiation dose of 5 kGy showed improved structural, mechanical, and thermal properties.
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