无催化剂条件下芳基硼酸与蒽的热促进环化反应：获得吖啶类化合物

IF 1 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Journal of Chemical Research Pub Date : 2024-02-05 DOI:10.1177/17475198241228252

Jing Jiang, Peng Xie, Yue Gao, Chenqi Wu, Jingcheng Song

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引用次数: 0

摘要

吖啶衍生物在有机光伏设备中具有广阔的应用前景。利用芳基硼酸从花青素中生产吖啶类化合物，开发出了一种高效、原子经济的合成方法。该方法无需催化剂，官能团耐受性好，操作简单。这种无催化剂工艺能以中等至较高的产率获得各种吖啶，为研究高温下的未开发反应提供了一个有效的平台。

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Thermo-promoted annulation of arylboronic acids with anthranils under catalyst-free conditions: Access to acridines

Acridine derivatives have exhibited great application prospects in organic photovoltaic devices. An efficient and atomically economical synthetic method was developed for the production of acridines from anthranils using arylboronic acids. This protocol features no catalysts, good functional group tolerance, and operational simplicity. This catalyst-free process afforded various acridines in moderate to good yields, providing an efficient platform for the investigation of untapped reactions at high temperatures.

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来源期刊

Journal of Chemical Research CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

2.30

自引率

0.00%

发文量

审稿时长

1.0 months

期刊介绍： The Journal of Chemical Research is a monthly journal which has a broad international authorship and publishes research papers and reviews in all branches of experimental chemistry. Established in 1977 as a joint venture by the British, French and German chemical societies it maintains the high standards set by the founding societies. Each paper is independently peer reviewed and only carefully evaluated contributions are accepted. Recent papers have described new synthetic methods, new heterocyclic compounds, new natural products, and the inorganic chemistry of metal complexes.