{"title":"利用化学共沉淀法制备 SnO2/TiO2 复合材料，用于亚甲基蓝的高效电催化氧化","authors":"","doi":"10.1007/s43153-024-00438-y","DOIUrl":null,"url":null,"abstract":"<h3>Abstract</h3> <p>In the present research, the Tin dioxide/Titanium dioxide (SnO<sub>2</sub>/TiO<sub>2</sub>) composite has been successfully fabricated by a chemical co-precipitation method. SnO<sub>2</sub>/TiO<sub>2</sub> composite precursors were calcined at different temperatures (400 °C, 500 °C 600 °C, 700 °C). The degradation experiment of methylene blue (MB) dye using SnO<sub>2</sub>/TiO<sub>2</sub> composite material was conducted to analyze the electrocatalytic performance. The degradation efficiency of the composite material can reach 96.6% (calcination at 500 °C). The logarithm of methylene blue concentration exhibits a strong linear relationship with reaction time, and the correlation coefficient R for each curve exceeds 0.99. This suggests that the electrocatalytic degradation process of methylene blue follows quasi-first order reaction kinetics. The ⋅OH present in the whole system can oxidize methylene blue (MB) into CO<sub>2</sub> and H<sub>2</sub>O, and the reaction is accompanied by oxygen evolution reaction. The inactive electrode has weak adsorption to the free ⋅OH, so the SnO<sub>2</sub>/TiO<sub>2</sub> electrode in the system has obvious advantages. The composite material electrode calcinated at 500 °C has the fastest electrocatalytic decolorization reaction rate and the highest catalytic capacity, which is consistent with the results of degradation efficiency.</p> <span> <h3>Graphical abstract</h3> <p> <span> <span> <img alt=\"\" src=\"https://static-content.springer.com/image/MediaObjects/43153_2024_438_Figa_HTML.png\"/> </span> </span></p> </span>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabrication of SnO2/TiO2 composite by a chemical co-precipitation method for efficient electrocatalytic oxidation of methylene blue\",\"authors\":\"\",\"doi\":\"10.1007/s43153-024-00438-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3>Abstract</h3> <p>In the present research, the Tin dioxide/Titanium dioxide (SnO<sub>2</sub>/TiO<sub>2</sub>) composite has been successfully fabricated by a chemical co-precipitation method. SnO<sub>2</sub>/TiO<sub>2</sub> composite precursors were calcined at different temperatures (400 °C, 500 °C 600 °C, 700 °C). The degradation experiment of methylene blue (MB) dye using SnO<sub>2</sub>/TiO<sub>2</sub> composite material was conducted to analyze the electrocatalytic performance. The degradation efficiency of the composite material can reach 96.6% (calcination at 500 °C). The logarithm of methylene blue concentration exhibits a strong linear relationship with reaction time, and the correlation coefficient R for each curve exceeds 0.99. This suggests that the electrocatalytic degradation process of methylene blue follows quasi-first order reaction kinetics. The ⋅OH present in the whole system can oxidize methylene blue (MB) into CO<sub>2</sub> and H<sub>2</sub>O, and the reaction is accompanied by oxygen evolution reaction. The inactive electrode has weak adsorption to the free ⋅OH, so the SnO<sub>2</sub>/TiO<sub>2</sub> electrode in the system has obvious advantages. The composite material electrode calcinated at 500 °C has the fastest electrocatalytic decolorization reaction rate and the highest catalytic capacity, which is consistent with the results of degradation efficiency.</p> <span> <h3>Graphical abstract</h3> <p> <span> <span> <img alt=\\\"\\\" src=\\\"https://static-content.springer.com/image/MediaObjects/43153_2024_438_Figa_HTML.png\\\"/> </span> </span></p> </span>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-02-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1007/s43153-024-00438-y\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1007/s43153-024-00438-y","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Fabrication of SnO2/TiO2 composite by a chemical co-precipitation method for efficient electrocatalytic oxidation of methylene blue
Abstract
In the present research, the Tin dioxide/Titanium dioxide (SnO2/TiO2) composite has been successfully fabricated by a chemical co-precipitation method. SnO2/TiO2 composite precursors were calcined at different temperatures (400 °C, 500 °C 600 °C, 700 °C). The degradation experiment of methylene blue (MB) dye using SnO2/TiO2 composite material was conducted to analyze the electrocatalytic performance. The degradation efficiency of the composite material can reach 96.6% (calcination at 500 °C). The logarithm of methylene blue concentration exhibits a strong linear relationship with reaction time, and the correlation coefficient R for each curve exceeds 0.99. This suggests that the electrocatalytic degradation process of methylene blue follows quasi-first order reaction kinetics. The ⋅OH present in the whole system can oxidize methylene blue (MB) into CO2 and H2O, and the reaction is accompanied by oxygen evolution reaction. The inactive electrode has weak adsorption to the free ⋅OH, so the SnO2/TiO2 electrode in the system has obvious advantages. The composite material electrode calcinated at 500 °C has the fastest electrocatalytic decolorization reaction rate and the highest catalytic capacity, which is consistent with the results of degradation efficiency.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
