0.1 兆帕时,288.15 至 343.15 K 范围内甘氨酸 + 1-醇(C2-C4)的密度、动态粘度和声速

IF 2.2 3区 工程技术 Q3 CHEMISTRY, PHYSICAL
Guadalupe Pérez-Durán , Gustavo A. Iglesias-Silva , José Julián Cano-Gómez , Mariana Ramos-Estrada
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引用次数: 0

摘要

在这项工作中,我们展示了深共晶溶剂(Glyceline)与 1-醇(C2-C4)在 0.1 兆帕(288.15 至 343.15)K 的实验密度、粘度和声速。密度和声速来自振动管密度计,动态粘度来自滚动球微粘度计。甘氨酸+1-丁醇的二元混合物呈现液-液分离。过剩摩尔体积、粘度偏差、声速偏差和等熵可压缩性偏差是通过实验测量计算得出的。过剩摩尔体积和粘度偏差在所有温度下均为负值。声速偏差为负值和正值。Redlich-Kister 方程用于将过剩摩尔体积与粘度、声速和等熵可压缩性偏差联系起来。我们使用 Akaike 信息标准对小样本进行校正,以获得 Redlich-Kister 方程中的最佳系数数。运动粘度使用 McAllister 和 Nava-Rios 方程进行关联。McAllister 公式的平均绝对百分比偏差为 3.09%,而 Nava-Rios 公式为 1.82%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Densities, dynamic viscosities, and speed of sound of glyceline + 1-alcohols (C2-C4) from 288.15 to 343.15 K at 0.1 MPa

Densities, dynamic viscosities, and speed of sound of glyceline + 1-alcohols (C2-C4) from 288.15 to 343.15 K at 0.1 MPa

In this work, we present experimental densities, viscosities, and speed of sound of a Deep Eutectic Solvent (Glyceline) with 1-alcohols (C2-C4) from (288.15 to 343.15) K at 0.1 MPa. Densities and speed of sound are from a vibrating tube densimeter while dynamic viscosities are from a rolling ball microviscosimeter. The binary mixture of Glyceline + 1-Butanol presents a liquid–liquid separation. Excess molar volumes, viscosity deviations, speed of sound deviations and isentropic compressibility deviations are calculated from experimental measurements. Excess molar volumes and viscosity deviations are negative at all temperatures. Speed of sound deviations are negative and positive. The Redlich-Kister equation is used to correlate the excess molar volume and the viscosity, speed of sound and isentropic compressibility deviations. We have used the Akaike Information Criterion corrected for small samples to obtain the optimal number of coefficients in the Redlich-Kister equation. Kinematic viscosities are correlated using the McAllister and the Nava-Rios equations. The average absolute percentage deviation of the McAllister equation is 3.09 % while for the Nava-Rios equation is 1.82 %.

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来源期刊
Journal of Chemical Thermodynamics
Journal of Chemical Thermodynamics 工程技术-热力学
CiteScore
5.60
自引率
15.40%
发文量
199
审稿时长
79 days
期刊介绍: The Journal of Chemical Thermodynamics exists primarily for dissemination of significant new knowledge in experimental equilibrium thermodynamics and transport properties of chemical systems. The defining attributes of The Journal are the quality and relevance of the papers published. The Journal publishes work relating to gases, liquids, solids, polymers, mixtures, solutions and interfaces. Studies on systems with variability, such as biological or bio-based materials, gas hydrates, among others, will also be considered provided these are well characterized and reproducible where possible. Experimental methods should be described in sufficient detail to allow critical assessment of the accuracy claimed. Authors are encouraged to provide physical or chemical interpretations of the results. Articles can contain modelling sections providing representations of data or molecular insights into the properties or transformations studied. Theoretical papers on chemical thermodynamics using molecular theory or modelling are also considered. The Journal welcomes review articles in the field of chemical thermodynamics but prospective authors should first consult one of the Editors concerning the suitability of the proposed review. Contributions of a routine nature or reporting on uncharacterised materials are not accepted.
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