Guadalupe Pérez-Durán , Gustavo A. Iglesias-Silva , José Julián Cano-Gómez , Mariana Ramos-Estrada
{"title":"0.1 兆帕时,288.15 至 343.15 K 范围内甘氨酸 + 1-醇(C2-C4)的密度、动态粘度和声速","authors":"Guadalupe Pérez-Durán , Gustavo A. Iglesias-Silva , José Julián Cano-Gómez , Mariana Ramos-Estrada","doi":"10.1016/j.jct.2024.107264","DOIUrl":null,"url":null,"abstract":"<div><p>In this work, we present experimental densities, viscosities, and speed of sound of a Deep Eutectic Solvent (Glyceline) with 1-alcohols (C<sub>2</sub>-C<sub>4</sub>) from (288.15 to 343.15) K at 0.1 MPa. Densities and speed of sound are from a vibrating tube densimeter while dynamic viscosities are from a rolling ball microviscosimeter. The binary mixture of Glyceline + 1-Butanol presents a liquid–liquid separation. Excess molar volumes, viscosity deviations, speed of sound deviations and isentropic compressibility deviations are calculated from experimental measurements. Excess molar volumes and viscosity deviations are negative at all temperatures. Speed of sound deviations are negative and positive. The Redlich-Kister equation is used to correlate the excess molar volume and the viscosity, speed of sound and isentropic compressibility deviations. We have used the Akaike Information Criterion corrected for small samples to obtain the optimal number of coefficients in the Redlich-Kister equation. Kinematic viscosities are correlated using the McAllister and the Nava-Rios equations. The average absolute percentage deviation of the McAllister equation is 3.09 % while for the Nava-Rios equation is 1.82 %.</p></div>","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"193 ","pages":"Article 107264"},"PeriodicalIF":2.2000,"publicationDate":"2024-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Densities, dynamic viscosities, and speed of sound of glyceline + 1-alcohols (C2-C4) from 288.15 to 343.15 K at 0.1 MPa\",\"authors\":\"Guadalupe Pérez-Durán , Gustavo A. Iglesias-Silva , José Julián Cano-Gómez , Mariana Ramos-Estrada\",\"doi\":\"10.1016/j.jct.2024.107264\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this work, we present experimental densities, viscosities, and speed of sound of a Deep Eutectic Solvent (Glyceline) with 1-alcohols (C<sub>2</sub>-C<sub>4</sub>) from (288.15 to 343.15) K at 0.1 MPa. Densities and speed of sound are from a vibrating tube densimeter while dynamic viscosities are from a rolling ball microviscosimeter. The binary mixture of Glyceline + 1-Butanol presents a liquid–liquid separation. Excess molar volumes, viscosity deviations, speed of sound deviations and isentropic compressibility deviations are calculated from experimental measurements. Excess molar volumes and viscosity deviations are negative at all temperatures. Speed of sound deviations are negative and positive. The Redlich-Kister equation is used to correlate the excess molar volume and the viscosity, speed of sound and isentropic compressibility deviations. We have used the Akaike Information Criterion corrected for small samples to obtain the optimal number of coefficients in the Redlich-Kister equation. Kinematic viscosities are correlated using the McAllister and the Nava-Rios equations. The average absolute percentage deviation of the McAllister equation is 3.09 % while for the Nava-Rios equation is 1.82 %.</p></div>\",\"PeriodicalId\":54867,\"journal\":{\"name\":\"Journal of Chemical Thermodynamics\",\"volume\":\"193 \",\"pages\":\"Article 107264\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-02-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Thermodynamics\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S002196142400017X\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Thermodynamics","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S002196142400017X","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Densities, dynamic viscosities, and speed of sound of glyceline + 1-alcohols (C2-C4) from 288.15 to 343.15 K at 0.1 MPa
In this work, we present experimental densities, viscosities, and speed of sound of a Deep Eutectic Solvent (Glyceline) with 1-alcohols (C2-C4) from (288.15 to 343.15) K at 0.1 MPa. Densities and speed of sound are from a vibrating tube densimeter while dynamic viscosities are from a rolling ball microviscosimeter. The binary mixture of Glyceline + 1-Butanol presents a liquid–liquid separation. Excess molar volumes, viscosity deviations, speed of sound deviations and isentropic compressibility deviations are calculated from experimental measurements. Excess molar volumes and viscosity deviations are negative at all temperatures. Speed of sound deviations are negative and positive. The Redlich-Kister equation is used to correlate the excess molar volume and the viscosity, speed of sound and isentropic compressibility deviations. We have used the Akaike Information Criterion corrected for small samples to obtain the optimal number of coefficients in the Redlich-Kister equation. Kinematic viscosities are correlated using the McAllister and the Nava-Rios equations. The average absolute percentage deviation of the McAllister equation is 3.09 % while for the Nava-Rios equation is 1.82 %.
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