Zoundi Ousmane, Nzihou Jean Fidele, Hamidou Salou, Ouattara Frederic, Segda Bila Gerard
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引用次数: 0
摘要
气化是从煤、生物质或固体废物等固体材料中产生可燃气体的过程。空间物理和能源实验室有两台实验气化器,用于生产合成气体,必须确定这些气体的性质和浓度。为此,购买了成本较低的传感器,用于测定一氧化碳的浓度,最大浓度为 1.000 和 2.000 ppm。这两款商用气体分析仪无法提供氢气和甲烷的浓度。本文使用金属氧化物气体传感器将一氧化碳的测量范围扩大到 4.000ppm。 此外,还可以测量木材燃烧同流下行气化炉产生的合成气体中的氢气和甲烷浓度,最高可达 10.000ppm。这些传感器的化学传感元件以二氧化锡(SnO2)层为基础,其电阻率对两个传感电极之间气体的性质非常敏感。这一特性为这些传感器提供了一个电阻电子模型,其测量值就是输入气体的浓度。这项研究表明,传感器的电阻 R 与气体浓度的关系式为:log(R/R0) = A log (x) +B。对于甲烷,A=-0.3072,B=0.921;对于二氧化碳,A=-0.6527,B=1.3055;对于氢气,A=-1.522,B=4.5686。
Design and Construction of a System for Measuring Carbon Monoxide, Hydrogen and Methane Concentrations in a Co-Current Downdraft Biomass Gasifier
Gasification is the process of producing combustible gases from solid materials such as coal, biomass or solid waste. The laboratory of Space Physics and Energy has two experimental gasifiers producing synthetic gases whose natures and concentrations must be determined. To do this, lower-cost sensors were purchased and used for determining the concentration of carbon monoxide with maximum concentration of 1.000 and 2.000 ppm. Hydrogen and methane concentration was not offered by these two commercial gas analyzers. In this paper Metal-Oxide gas sensors were used to extend the measurement range of carbon monoxide up to 4.000ppm. Hydrogen and methane concentrations up to 10.000ppm in synthetic gas produced by a wood fired co-current downdraft gasifier measurements were also enabled. These sensors have a chemical sensing element based on a layer of tin dioxide (SnO2); whose resistivity is sensitive to nature of the gas between two sensing electrodes. This property gives these sensors a resistive electrical model whose measurand is the concentration of the input gas. This study shows that resistor R of the sensor is related to the gas concentration with an equation of the form: log(R/R0) = A log (x) +B. With A= -0.3072, B = 0.921 for methane, A= -0.6527, B=1.3055 for carbon dioxide and A= -1.522, B = 4.5686 for hydrogen.