热改性透平碳对其分形结构的影响

V. Mandzyuk, R. Lisovskiy, Yu.O. Kulyk, B. Rachiy, R.V. Solomovskyi
{"title":"热改性透平碳对其分形结构的影响","authors":"V. Mandzyuk, R. Lisovskiy, Yu.O. Kulyk, B. Rachiy, R.V. Solomovskyi","doi":"10.15330/pcss.25.1.51-56","DOIUrl":null,"url":null,"abstract":"Fractal structure of porous carbon materials (PCMs) obtained by thermal modification under different regimes was investigated using the method of low-temperature porometry. It was established that at modification temperatures of 300 and 600°C, materials with a developed microporous structure are formed, the surface fractal dimension of which is 2.6. At modification temperatures of 400 and 500°C, the value of the fractal dimension of the surface decreases to a value of 2.22, which indicates the formation of an almost smooth surface due to the intensive removal of carbon atoms from the near-surface layers of the material particles, a decrease in the number of micropores with their transition into mesopores, unification of small carbon clusters into larger ones and the formation of microparticles of non-porous carbon material.","PeriodicalId":509433,"journal":{"name":"Physics and Chemistry of Solid State","volume":"4 2","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The effect of thermal modification of turbostratic carbon on its fractal structure\",\"authors\":\"V. Mandzyuk, R. Lisovskiy, Yu.O. Kulyk, B. Rachiy, R.V. Solomovskyi\",\"doi\":\"10.15330/pcss.25.1.51-56\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Fractal structure of porous carbon materials (PCMs) obtained by thermal modification under different regimes was investigated using the method of low-temperature porometry. It was established that at modification temperatures of 300 and 600°C, materials with a developed microporous structure are formed, the surface fractal dimension of which is 2.6. At modification temperatures of 400 and 500°C, the value of the fractal dimension of the surface decreases to a value of 2.22, which indicates the formation of an almost smooth surface due to the intensive removal of carbon atoms from the near-surface layers of the material particles, a decrease in the number of micropores with their transition into mesopores, unification of small carbon clusters into larger ones and the formation of microparticles of non-porous carbon material.\",\"PeriodicalId\":509433,\"journal\":{\"name\":\"Physics and Chemistry of Solid State\",\"volume\":\"4 2\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-02-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physics and Chemistry of Solid State\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15330/pcss.25.1.51-56\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physics and Chemistry of Solid State","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15330/pcss.25.1.51-56","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

利用低温测孔法研究了在不同条件下通过热改性获得的多孔碳材料(PCMs)的分形结构。结果表明,在改性温度为 300 和 600°C 时,形成的材料具有发达的微孔结构,其表面分形维数为 2.6。在改性温度为 400 和 500°C 时,表面分形维度值降至 2.22,这表明由于材料颗粒近表面层碳原子的大量清除,形成了几乎光滑的表面,微孔数量减少并过渡到中孔,小碳团聚成大碳团聚,形成了无孔碳材料微粒。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The effect of thermal modification of turbostratic carbon on its fractal structure
Fractal structure of porous carbon materials (PCMs) obtained by thermal modification under different regimes was investigated using the method of low-temperature porometry. It was established that at modification temperatures of 300 and 600°C, materials with a developed microporous structure are formed, the surface fractal dimension of which is 2.6. At modification temperatures of 400 and 500°C, the value of the fractal dimension of the surface decreases to a value of 2.22, which indicates the formation of an almost smooth surface due to the intensive removal of carbon atoms from the near-surface layers of the material particles, a decrease in the number of micropores with their transition into mesopores, unification of small carbon clusters into larger ones and the formation of microparticles of non-porous carbon material.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信