{"title":"交联聚合物的 z 平均值","authors":"Rolf Bachmann","doi":"10.1002/mats.202300065","DOIUrl":null,"url":null,"abstract":"Stockmayer's formula for the weight average of cross‐linked primary chains was extended to the z‐average degree of polymerization DPz. This average is a function of the weight‐ and z‐average degree of polymerization λw and λz of the primary chain distribution and the branching density α: Higher averages of branched polymers from monomers of type Af and BAf − 1 with functionalities f ⩾ 2 are discussed.This article is protected by copyright. All rights reserved","PeriodicalId":18157,"journal":{"name":"Macromolecular Theory and Simulations","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The z‐Average of Cross‐Linked Polymers\",\"authors\":\"Rolf Bachmann\",\"doi\":\"10.1002/mats.202300065\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Stockmayer's formula for the weight average of cross‐linked primary chains was extended to the z‐average degree of polymerization DPz. This average is a function of the weight‐ and z‐average degree of polymerization λw and λz of the primary chain distribution and the branching density α: Higher averages of branched polymers from monomers of type Af and BAf − 1 with functionalities f ⩾ 2 are discussed.This article is protected by copyright. All rights reserved\",\"PeriodicalId\":18157,\"journal\":{\"name\":\"Macromolecular Theory and Simulations\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-02-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Theory and Simulations\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1002/mats.202300065\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Theory and Simulations","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/mats.202300065","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
摘要
斯托克迈尔的交联主链重量平均值公式被扩展到 z 平均聚合度 DPz。该平均值是主链分布的重量平均聚合度 λw 和 z 平均聚合度 λz 以及支化密度 α 的函数:本文受版权保护。本文受版权保护。
Stockmayer's formula for the weight average of cross‐linked primary chains was extended to the z‐average degree of polymerization DPz. This average is a function of the weight‐ and z‐average degree of polymerization λw and λz of the primary chain distribution and the branching density α: Higher averages of branched polymers from monomers of type Af and BAf − 1 with functionalities f ⩾ 2 are discussed.This article is protected by copyright. All rights reserved
期刊介绍:
Macromolecular Theory and Simulations is the only high-quality polymer science journal dedicated exclusively to theory and simulations, covering all aspects from macromolecular theory to advanced computer simulation techniques.