乙二胺四乙酸三钠水溶液与 EG、DEG 和 TEG 的体积和声学特性与温度有关

Manisha Lamba , Nabaparna Chakraborty , K.C. Juglan , Meenu Singla
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引用次数: 0

摘要

根据乙二胺四乙酸三钠溶液(水溶液)中乙二醇(EG)、二甘醇(DEG)和三甘醇(TEG)的密度(ρ)和声速(s)在(288.15、298.15、308.15 和 318.15)K 和 0.01 MPa 下的密度 (ρ)和声速 (s) 的实验值进行了估算。从无限稀释极限表观摩尔体积(Vϕ∘)和等熵可压缩性(Kϕ,s∘)的基础出发,计算其传递特性(ΔVϕ∘, ΔKϕ,s∘)、膨胀系数(∂Eϕ∘/∂T)P、在此基础上,研究并解决了乙二醇和 EDTA 在水溶液中的膨胀系数 (α)和相互作用系数 (VAB,KAB,VABB,KABB)。还在二元溶液中进行了傅立叶变换红外光谱研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Volumetric and acoustic characteristics of a temperature-dependent aqueous solution of trisodium EDTA with EG, DEG and TEG

Volumetric and acoustic characteristics of a temperature-dependent aqueous solution of trisodium EDTA with EG, DEG and TEG

The apparent molar volume(Vϕ) and apparent molar isentropic compressibility (Kϕ,s) of ethylene glycol (EG), diethylene glycol (DEG) and triethylene glycol (TEG) in trisodium ethylenediaminetetraacetic acid solution (aqueous) have been estimated based on measured experiments values for both the density (ρ) and sound speed (s) at (288.15, 298.15, 308.15 and 318.15) K and 0.01 MPa as well. From the foundation in infinite dilution limiting apparent molar volumes (Vϕ) and isentropic compressibility(Kϕ,s) its transfer properties (ΔVϕ, ΔKϕ,s), expansibility coefficients(Eϕ/T)P, expansion coefficient (α) and interactions coefficients (VAB,KAB,VABB,KABB) the various interactions among glycols and EDTA in aqueous solution were investigated and addressed. Fourier transform infrared spectroscopy study had also been carried in binary solution.

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