利用 SrSi2O2N2:Eu2+,Yb2+ 荧光粉实现高显色指数和高色调稳定性

Ha Thanh Tung, Dieu An Nguyen Thi
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摘要

针对白光发光二极管(WLED)的应用,我们研制出了一种从绿色到橙色的氮硅酸盐荧光粉。观察到的绿橙范围宽带辐射是由双掺杂 SrSi2O2N2:Eu2+,Yb2+ (SSON:Eu,Yb) 氮硅酸盐荧光粉阱点的 Eu2+ 和 Yb2+ 造成的。测量了绿光辐射的衰减时间,以验证激活剂离子之间的能量传递。研究了不同掺杂比例的活化剂离子对发光特性的影响。所得荧光粉的辐射是活化剂离子浓度的函数,提高 Yb2+ 浓度会导致红光辐射优先于绿光辐射。为了产生白光照明,将所得荧光粉与泵浦波长为 450 nm 的 InGaN 蓝光 LED 芯片耦合。实现色调平衡管理分为两个阶段。首先,通过改变 Eu2+ 和 Yb2+ 离子的浓度来调整绿色和橙色的比例。第二阶段,通过增加荧光粉的用量,将国际照明委员会(CIE)的坐标从[0.2805; 0.2014]改为[0.4071; 03789]。在最佳条件下产生的白色照明的色调显现指标为 89。所设计的单级双色调释放ridosilicate 荧光粉和蓝光 LED 芯片在较宽的正向偏置电流范围内(3 V 时 100 至 500 mA)显示出显著的色调稳定性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Utilizing SrSi2O2N2:Eu2+,Yb2+ phosphor to achieve high hue rendering index and high hue stability
For white-light emitting diode (WLED) applications, a green-to-orange emission nitridosilicate-based phosphor is created. The observed wide-band radiation in the green-orange range is caused by Eu2+ and Yb2+ at the trap point of a doubly doped SrSi2O2N2:Eu2+,Yb2+ (SSON:Eu,Yb) nitridosilicate phosphor. The green-color radiation’s decay duration was measured to validate the energy transfer among activator ions. The co-doping various ratios’ influence of activator ions on luminescence features was investigated. The resulting phosphor’s radiation is a function of the activator ion concentrations and raising the Yb2+ concentration causes red-color radiation to dominate the green radiation. To generate white illumination, the resulting phosphor was coupled with an InGaN blue-LED chip having a pumping wavelength of 450 nm. Two stages were taken to achieve hue balance management. Initially, the green to orange proportion was tuned by varying the Eu2+ and Yb2+ ions’ concentrations. At the second stage, the Commission Internationale de L’Eclairage, International Commission on Illumination (CIE) coordinates were changed from [0.2805; 0.2014] to [0.4071; 03789] by raising the amount of phosphor powder used. White illumination produced under optimal conditions has a hue rendering indicator of 89. The designed single-stage dual-hue-releasing nitridosilicate phosphor and blue-LED chip displayed remarkable hue steadiness over a wideband of forward-bias currents (100 to 500 mA at 3 V).
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