铑催化 N-氟苯磺酰亚胺与 2,4-二芳基喹唑啉的 C-H 选择性胺化反应

IF 1 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Journal of Chemical Research Pub Date : 2024-01-01 DOI:10.1177/17475198231226425

Wei-Ming Gao, Lifang Hu, Fang Gao, Guozhu Hu, Xueying Zhou

引用次数: 0

摘要

以市场上可买到的 N-氟苯磺酰亚胺为氨基源，开发了一种铑催化的 2,4-二芳基喹唑啉的 C-H 选择性酰胺化反应。这种方法为直接 C-H 酰胺化提供了一条独特的途径，并表现出显著的官能团耐受性和区域选择性。

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Rhodium-catalyzed C–H selective amination of 2,4-diarylquinazolines with N-fluorobenzenesulfonimide

A rhodium-catalyzed C–H selective amination of 2,4-diarylquinazolines has been developed with the commercially available N-fluorobenzenesulfonimide as the amino source. This approach offers a unique route for direct C–H amidation and demonstrates remarkable functional group tolerance and regioselectivity.

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来源期刊

Journal of Chemical Research CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

2.30

自引率

0.00%

发文量

审稿时长

1.0 months

期刊介绍： The Journal of Chemical Research is a monthly journal which has a broad international authorship and publishes research papers and reviews in all branches of experimental chemistry. Established in 1977 as a joint venture by the British, French and German chemical societies it maintains the high standards set by the founding societies. Each paper is independently peer reviewed and only carefully evaluated contributions are accepted. Recent papers have described new synthetic methods, new heterocyclic compounds, new natural products, and the inorganic chemistry of metal complexes.