优化 Sr2Co2O5/rGO 复合电极的充电动力学:重新定义超级电容器效率

Muhammad Bilal, Farooq Ahmad, Sidra Zawar, Umer Waqas, Muhammad Ahmed Khan, S. Ramay, S. Atiq
{"title":"优化 Sr2Co2O5/rGO 复合电极的充电动力学:重新定义超级电容器效率","authors":"Muhammad Bilal, Farooq Ahmad, Sidra Zawar, Umer Waqas, Muhammad Ahmed Khan, S. Ramay, S. Atiq","doi":"10.1149/2162-8777/ad2110","DOIUrl":null,"url":null,"abstract":"\n Mixed transition metal oxides have become highly effective electrode materials due to their remarkable cyclic stability and improved capacitance, which has consequently lead them to display exceptional electrochemical performance. In this work, a facile synthesis of Sr2Fe2O5/reduced graphene oxide composites was carried out through solvothermal technique to investigate the electrochemical performance. X-ray diffraction patterns confirmed cubic perovskite structure of Sr2Fe2O5. The morphological analysis revealed well-defined grains with sharp boundaries, having uniformly distributed porous regions. The stoichiometric ratios of sample compositions were confirmed using elemental analysis. The electrolyte employed for the electrochemical characterizations was 1 M potassium hydroxide (KOH), carried-out using three-electrode cell. The composite sample Sr2Fe2O5/15% reduced graphene oxide showed excellent electrochemical performance compared to other samples. It demonstrated maximum specific capacitance of ⁓360.29 F g−1 at a lower scan rate of 0.01 V s−1, as observed using cyclic voltammetry. The electrochemical analysis of this electrode through the GCD system has a high value of capacitance ⁓1110 F g−1 followed by a high energy density value of ⁓32.76 Wh/kg, respectively. The Nyquist plot revealed less barrier to charge transfer. Therefore, the comprehensive investigation of this electrode material suggested that this as-synthesized composite could be utilized in high-performance energy storage devices.","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optimized Charge Dynamics of Sr2Co2O5/rGO Composite Electrodes: Redefining Supercapacitor Efficiency\",\"authors\":\"Muhammad Bilal, Farooq Ahmad, Sidra Zawar, Umer Waqas, Muhammad Ahmed Khan, S. Ramay, S. Atiq\",\"doi\":\"10.1149/2162-8777/ad2110\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n Mixed transition metal oxides have become highly effective electrode materials due to their remarkable cyclic stability and improved capacitance, which has consequently lead them to display exceptional electrochemical performance. In this work, a facile synthesis of Sr2Fe2O5/reduced graphene oxide composites was carried out through solvothermal technique to investigate the electrochemical performance. X-ray diffraction patterns confirmed cubic perovskite structure of Sr2Fe2O5. The morphological analysis revealed well-defined grains with sharp boundaries, having uniformly distributed porous regions. The stoichiometric ratios of sample compositions were confirmed using elemental analysis. The electrolyte employed for the electrochemical characterizations was 1 M potassium hydroxide (KOH), carried-out using three-electrode cell. The composite sample Sr2Fe2O5/15% reduced graphene oxide showed excellent electrochemical performance compared to other samples. It demonstrated maximum specific capacitance of ⁓360.29 F g−1 at a lower scan rate of 0.01 V s−1, as observed using cyclic voltammetry. The electrochemical analysis of this electrode through the GCD system has a high value of capacitance ⁓1110 F g−1 followed by a high energy density value of ⁓32.76 Wh/kg, respectively. The Nyquist plot revealed less barrier to charge transfer. Therefore, the comprehensive investigation of this electrode material suggested that this as-synthesized composite could be utilized in high-performance energy storage devices.\",\"PeriodicalId\":504734,\"journal\":{\"name\":\"ECS Journal of Solid State Science and Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-01-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ECS Journal of Solid State Science and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1149/2162-8777/ad2110\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ECS Journal of Solid State Science and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1149/2162-8777/ad2110","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

混合过渡金属氧化物因其显著的循环稳定性和更高的电容而成为高效电极材料,并因此显示出卓越的电化学性能。本研究通过溶热技术轻松合成了 Sr2Fe2O5/还原氧化石墨烯复合材料,并对其电化学性能进行了研究。X 射线衍射图样证实了 Sr2Fe2O5 的立方包晶结构。形态分析表明,晶粒清晰,边界锐利,具有均匀分布的多孔区域。通过元素分析确认了样品成分的化学计量比。电化学特性分析采用的电解质是 1 M 氢氧化钾(KOH),使用三电极电池进行。与其他样品相比,Sr2Fe2O5/15% 还原氧化石墨烯复合样品表现出优异的电化学性能。根据循环伏安法的观察,在 0.01 V s-1 的较低扫描速率下,它的最大比电容为 ⁓360.29 F g-1。通过 GCD 系统对该电极进行的电化学分析显示,其电容值⁓1110 F g-1 较高,能量密度值⁓32.76 Wh/kg。奈奎斯特图显示电荷转移障碍较小。因此,对这种电极材料的综合研究表明,这种合成的复合材料可用于高性能储能装置。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optimized Charge Dynamics of Sr2Co2O5/rGO Composite Electrodes: Redefining Supercapacitor Efficiency
Mixed transition metal oxides have become highly effective electrode materials due to their remarkable cyclic stability and improved capacitance, which has consequently lead them to display exceptional electrochemical performance. In this work, a facile synthesis of Sr2Fe2O5/reduced graphene oxide composites was carried out through solvothermal technique to investigate the electrochemical performance. X-ray diffraction patterns confirmed cubic perovskite structure of Sr2Fe2O5. The morphological analysis revealed well-defined grains with sharp boundaries, having uniformly distributed porous regions. The stoichiometric ratios of sample compositions were confirmed using elemental analysis. The electrolyte employed for the electrochemical characterizations was 1 M potassium hydroxide (KOH), carried-out using three-electrode cell. The composite sample Sr2Fe2O5/15% reduced graphene oxide showed excellent electrochemical performance compared to other samples. It demonstrated maximum specific capacitance of ⁓360.29 F g−1 at a lower scan rate of 0.01 V s−1, as observed using cyclic voltammetry. The electrochemical analysis of this electrode through the GCD system has a high value of capacitance ⁓1110 F g−1 followed by a high energy density value of ⁓32.76 Wh/kg, respectively. The Nyquist plot revealed less barrier to charge transfer. Therefore, the comprehensive investigation of this electrode material suggested that this as-synthesized composite could be utilized in high-performance energy storage devices.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信