(4-丁基-1-乙基-1,2,4-三唑-5-亚基)[(1,2,5,6-η)-环辛烷-1,5-二烯](三苯基膦)四氟硼酸铑(I)

IUCrData Pub Date : 2024-01-01 DOI:10.1107/S2414314624000609

Timothy G. Lerch , Michael Gau , Daniel R. Albert , Edward Rajaseelan , W. T. A. Harrison (Editor)

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引用次数: 0

摘要

在标题为[Rh(C8H12)(C8H15N3)(C18H15P)]BF4 的三唑基 N-heterocyclic carbene 铑(I)阳离子配合物与四氟硼酸反离子中，结晶不对称单元中有两个阳离子和两个阴离子。几种非典型的 C-H...F 氢键相互作用有助于巩固堆积。其中一个阴离子的两个 F 原子以 0.814 (4):0.186 (4) 的比例无序地分布在相邻位点上。

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(4-Butyl-1-ethyl-1,2,4-triazol-5-ylidene)[(1,2,5,6-η)-cycloocta-1,5-diene](triphenylphosphane)rhodium(I) tetrafluoridoborate

In the title triazole-based N-heterocyclic carbene rhodium(I) cationic complex with a tetrafluoridoborate counter-anion, the Rh center has a distorted square-planar coordination geometry with expected bond distances.

In the title triazole-based N-heterocyclic carbene rhodium(I) cationic complex with a tetrafluoridoborate counter-anion, [Rh(C₈H₁₂)(C₈H₁₅N₃)(C₁₈H₁₅P)]BF₄, which crystallizes with two cations and two anions in the asymmetric unit, the Rh center has a distorted square-planar coordination geometry with expected bond distances. Several nonclassical C—H⋯F hydrogen-bonding interactions help to consolidate the packing. Two of the F atoms of one of the anions are disordered over adjacent sites in a 0.814 (4):0.186 (4) ratio.

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来源期刊

IUCrData

CiteScore

0.30

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0.00%

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