通过热[2 + 2]-环加成法实现硼烷化环丁烷

IF 7.6 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chemical Science Pub Date : 2024-01-25 DOI:10.1039/D3SC06600B

Kateryna Prysiazhniuk, Oleksandr Polishchuk, Stanislav Shulha, Kyrylo Gudzikevych, Oleksandr P. Datsenko, Vladimir Kubyshkin and Pavel K. Mykhailiuk

引用次数: 0

摘要

本文详细阐述了从羧酸酰胺和乙烯基硼酸酯一步法制备硼化环丁烷的方法。该反应通过原位生成的酮亚胺盐的热[2 + 2]-环加成反应进行。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Borylated cyclobutanes via thermal [2 + 2]-cycloaddition†

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Borylated cyclobutanes via thermal [2 + 2]-cycloaddition†

A one-step approach to borylated cyclobutanes from amides of carboxylic acids and vinyl boronates is elaborated. The reaction proceeds via the thermal [2 + 2]-cycloaddition of in situ-generated keteniminium salts.

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来源期刊

Chemical Science CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

14.40

自引率

4.80%

发文量

1352

审稿时长

2.1 months

期刊介绍： Chemical Science is a journal that encompasses various disciplines within the chemical sciences. Its scope includes publishing ground-breaking research with significant implications for its respective field, as well as appealing to a wider audience in related areas. To be considered for publication, articles must showcase innovative and original advances in their field of study and be presented in a manner that is understandable to scientists from diverse backgrounds. However, the journal generally does not publish highly specialized research.