利用油茶籽生物合成银、金和钯纳米粒子:探索光催化、催化和抗菌活性

IF 1.7 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
M S Anandha Prabhu, G Edwin Sheela, Abeer M Mohammad, Rabab A Hegazy, S Sasi Florence, V Sarojini
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引用次数: 0

摘要

在本研究中,我们探索了利用油辣木籽(MOS)提取物绿色合成金属纳米粒子(Ag-NPs、Au-NPs 和 Pd-NPs)的方法。油辣木籽因其营养密度高、抗氧化性强、抗炎效果好以及在控制胆固醇和血糖水平、促进消化、皮肤和头发健康方面具有潜在益处而闻名。通过改变 MOS 提取物的浓度来控制纳米粒子的大小。通过表面等离子体共振(SPR)证实了 Au-NPs 和 Ag-NPs 的成功形成,而 420 纳米处没有吸收表明 Pd2+ 离子被还原成 Pd0,从而证实了 Pd-NPs 的合成。纳米粒子呈单分散球形,结晶度得到证实。经测定,Pd-NPs 的尺寸为 28 nm,Au-NPs 为 5 nm,Ag-NPs 为 19 nm。MOS 提取物中的酚类和蛋白质在还原和稳定 Ag-NPs、Au-NPs 和 Pd-NPs 方面发挥了重要作用。值得注意的是,合成的纳米粒子具有很强的抗菌活性,特别是对伤寒沙门氏菌,使其成为潜在的抗菌剂。利用 NaBH4 将 4-硝基苯酚(4-NP)还原为 4-氨基苯酚,研究了 Au-NPs、Ag-NPs 和 Pd-NPs 的催化效率。结果表明,Ag-NPs 和 Pd-NPs 的光催化降解率常数和催化反应率常数分别为 0.0038/min 和 0.261/min,而 Au-NPs 的光催化降解率常数和催化反应率常数分别为 0.0038/min 和 0.261/min。通过将绿色合成方法与对其特性和多样化应用的深入分析相结合,本研究为 MOS 辅助金属纳米粒子在各种技术和环境进步方面的巨大潜力提供了宝贵的见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Biogenic synthesis of silver, gold, and palladium nanoparticles using moringa oleifera seeds: exploring photocatalytic, catalytic, and antimicrobial activities
In this study, we explored the green synthesis of metal nanoparticles (Ag-NPs, Au-NPs, and Pd-NPs) using Moringa oleifera seed (MOS) extract, which is known for its nutrient density, antioxidant properties, anti-inflammatory effects, and potential benefits in managing cholesterol, blood sugar levels, as well as promoting digestion, skin, and hair health. The nanoparticles’ size was controlled by varying the concentration of MOS extract. The successful formation of Au-NPs and Ag-NPs was confirmed through surface plasmon resonance (SPR), while the absence of absorption at 420 nm indicated the reduction of Pd2+ ions to Pd0, affirming the synthesis of Pd-NPs. The nanoparticles exhibited mono-dispersed, spherical shapes with confirmed crystallinity. Sizes were determined as 28 nm for Pd-NPs, 5 nm for Au-NPs, and 19 nm for Ag-NPs. The MOS extract’s phenols and proteins played a crucial role in reducing and stabilising Ag-NPs, Au-NPs, and Pd-NPs. Notably, the synthesised nanoparticles demonstrated strong antimicrobial activity, particularly against Salmonella typhi, making them potential antibacterial agents. The catalytic efficiency of Au-NPs, Ag-NPs and Pd-NPs was studied using the reduction of 4-Nitrophenol (4-NP) by NaBHto 4-Aminophenol. Additionally, Au-NPs showed enhanced photocatalytic degradation rate constant and catalytic reaction rate constant of 0.0038/min and 0.261/min respectively, due to their small size and increased surface area. By combining a green synthesis approach with an in-depth analysis of properties and diverse applications, this study provides valuable insights into the immense potential of MOS-assisted metal nanoparticles for various technological and environmental advancements.
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来源期刊
Advances in Natural Sciences: Nanoscience and Nanotechnology
Advances in Natural Sciences: Nanoscience and Nanotechnology NANOSCIENCE & NANOTECHNOLOGYMATERIALS SCIE-MATERIALS SCIENCE, MULTIDISCIPLINARY
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