M. A. Medkov, G. F. Krysenko, D. G. Epov, E. E. Dmitrieva, E. B. Merkulov
{"title":"含钨矿物原料与氟化氢铵和硫酸盐混合物的相互作用","authors":"M. A. Medkov, G. F. Krysenko, D. G. Epov, E. E. Dmitrieva, E. B. Merkulov","doi":"10.1134/s0040579523320039","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The interaction of tungsten mineral raw materials with a mixture of NH<sub>4</sub>HF<sub>2</sub> and (NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub> upon heating was studied. It was determined that, first, at temperatures up to 200°C, the incoming components are fluorinated to form complex and simple fluorides. A further increase in temperature is accompanied by the decomposition of ammonium sulfate to form NH<sub>4</sub>HSO<sub>4</sub>, which leads to the conversion of fluorides into sulfates and of the tungsten ammonium fluoride complex into tungstic acid H<sub>2</sub>WO<sub>4</sub>. It was shown that water leaching of the product of the decomposition of tungsten-containing mineral raw materials with a mixture of NH<sub>4</sub>HF<sub>2</sub> and (NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub> makes it possible to extract tungsten from mineral raw materials in the form of the commercial product WO<sub>3</sub>.</p>","PeriodicalId":798,"journal":{"name":"Theoretical Foundations of Chemical Engineering","volume":"13 1","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2024-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Interaction of Tungsten-Containing Mineral Raw Materials with a Mixture of Ammonium Bifluoride and Sulfate\",\"authors\":\"M. A. Medkov, G. F. Krysenko, D. G. Epov, E. E. Dmitrieva, E. B. Merkulov\",\"doi\":\"10.1134/s0040579523320039\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>The interaction of tungsten mineral raw materials with a mixture of NH<sub>4</sub>HF<sub>2</sub> and (NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub> upon heating was studied. It was determined that, first, at temperatures up to 200°C, the incoming components are fluorinated to form complex and simple fluorides. A further increase in temperature is accompanied by the decomposition of ammonium sulfate to form NH<sub>4</sub>HSO<sub>4</sub>, which leads to the conversion of fluorides into sulfates and of the tungsten ammonium fluoride complex into tungstic acid H<sub>2</sub>WO<sub>4</sub>. It was shown that water leaching of the product of the decomposition of tungsten-containing mineral raw materials with a mixture of NH<sub>4</sub>HF<sub>2</sub> and (NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub> makes it possible to extract tungsten from mineral raw materials in the form of the commercial product WO<sub>3</sub>.</p>\",\"PeriodicalId\":798,\"journal\":{\"name\":\"Theoretical Foundations of Chemical Engineering\",\"volume\":\"13 1\",\"pages\":\"\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2024-01-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical Foundations of Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1134/s0040579523320039\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical Foundations of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1134/s0040579523320039","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Interaction of Tungsten-Containing Mineral Raw Materials with a Mixture of Ammonium Bifluoride and Sulfate
Abstract
The interaction of tungsten mineral raw materials with a mixture of NH4HF2 and (NH4)2SO4 upon heating was studied. It was determined that, first, at temperatures up to 200°C, the incoming components are fluorinated to form complex and simple fluorides. A further increase in temperature is accompanied by the decomposition of ammonium sulfate to form NH4HSO4, which leads to the conversion of fluorides into sulfates and of the tungsten ammonium fluoride complex into tungstic acid H2WO4. It was shown that water leaching of the product of the decomposition of tungsten-containing mineral raw materials with a mixture of NH4HF2 and (NH4)2SO4 makes it possible to extract tungsten from mineral raw materials in the form of the commercial product WO3.
期刊介绍：
Theoretical Foundations of Chemical Engineering is a comprehensive journal covering all aspects of theoretical and applied research in chemical engineering, including transport phenomena; surface phenomena; processes of mixture separation; theory and methods of chemical reactor design; combined processes and multifunctional reactors; hydromechanic, thermal, diffusion, and chemical processes and apparatus, membrane processes and reactors; biotechnology; dispersed systems; nanotechnologies; process intensification; information modeling and analysis; energy- and resource-saving processes; environmentally clean processes and technologies.
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