氢氧化硼酸锌的合成与结构改进：Zn3B7O13(OH)

Zeitschrift für Naturforschung B Pub Date : 2024-01-01 DOI:10.1515/znb-2023-0096

Raimund Ziegler, Sabrina Jungmann, H. Huppertz

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引用次数: 0

摘要

摘要新型硼酸锌 Zn3B7O13(OH)在空间群 R3c（编号 161）中呈三棱结晶，其晶格参数为 a = 849.76(3)，c = 2099.8(2) pm，V = 1.3131(2) nm3，每个单元格有六个公式单位（Z = 6）。它是在高压/高温条件下，在多管装置中合成的。进行了单晶和粉末 X 射线衍射实验。

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Synthesis and structure refinement of the zinc hydroxide boracite: Zn3B7O13(OH)

Abstract The new zinc borate Zn3B7O13(OH) crystallizes trigonally in the space group R3c (no. 161) with the lattice parameters a = 849.76(3), c = 2099.8(2) pm, V = 1.3131(2) nm3, and six formula units per unit cell (Z = 6). It was synthesized at high-pressure/high-temperature conditions in a multianvil device. Single-crystal and powder X-ray diffraction experiments were conducted.

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Zeitschrift für Naturforschung B

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