Ligang Xu , Wenda Zhang , Chenjie Lou , Chenxu Geng , Yuxiu Sun , Jie Liu , Yongchao Shi , Huajie Luo , Jipeng Fu , Haiyan Zheng , Mingxue Tang
{"title":"揭示离子液体与金属有机框架基质之间的结构相关性","authors":"Ligang Xu , Wenda Zhang , Chenjie Lou , Chenxu Geng , Yuxiu Sun , Jie Liu , Yongchao Shi , Huajie Luo , Jipeng Fu , Haiyan Zheng , Mingxue Tang","doi":"10.1016/j.mrl.2023.12.003","DOIUrl":null,"url":null,"abstract":"<div><p>Solid-state batteries are rising rapidly in response to the fast-increasing energy demand. Metal-organic framework (MOF) loaded with ionic liquids has brought new opportunities for solid-state batteries owing to its good interfacial compatibility and high ionic conductivity. MOF-808 is selected to be filled with Li-contained ionic liquid for structure and ion dynamics investigation using nuclear magnetic resonance (NMR) and X-ray diffraction. This study finds that the introduced ionic liquid would partially soften the matrix of MOF-808 and thus yield amorphous phase. By selective isotope replacement under cycling symmetric <sup>6</sup>Li metal cell, Li<sup>+</sup> ion is observed to mainly go cross ionic liquid in the open channel of matrix under potential polarization.</p></div>","PeriodicalId":93594,"journal":{"name":"Magnetic Resonance Letters","volume":"4 2","pages":"Article 100095"},"PeriodicalIF":0.0000,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772516224000020/pdfft?md5=b55282bb5d9072c27f0c79257107412f&pid=1-s2.0-S2772516224000020-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Revealing structure correlation between ionic liquid and metal-organic framework matrix\",\"authors\":\"Ligang Xu , Wenda Zhang , Chenjie Lou , Chenxu Geng , Yuxiu Sun , Jie Liu , Yongchao Shi , Huajie Luo , Jipeng Fu , Haiyan Zheng , Mingxue Tang\",\"doi\":\"10.1016/j.mrl.2023.12.003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Solid-state batteries are rising rapidly in response to the fast-increasing energy demand. Metal-organic framework (MOF) loaded with ionic liquids has brought new opportunities for solid-state batteries owing to its good interfacial compatibility and high ionic conductivity. MOF-808 is selected to be filled with Li-contained ionic liquid for structure and ion dynamics investigation using nuclear magnetic resonance (NMR) and X-ray diffraction. This study finds that the introduced ionic liquid would partially soften the matrix of MOF-808 and thus yield amorphous phase. By selective isotope replacement under cycling symmetric <sup>6</sup>Li metal cell, Li<sup>+</sup> ion is observed to mainly go cross ionic liquid in the open channel of matrix under potential polarization.</p></div>\",\"PeriodicalId\":93594,\"journal\":{\"name\":\"Magnetic Resonance Letters\",\"volume\":\"4 2\",\"pages\":\"Article 100095\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2772516224000020/pdfft?md5=b55282bb5d9072c27f0c79257107412f&pid=1-s2.0-S2772516224000020-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Magnetic Resonance Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2772516224000020\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Magnetic Resonance Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772516224000020","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Revealing structure correlation between ionic liquid and metal-organic framework matrix
Solid-state batteries are rising rapidly in response to the fast-increasing energy demand. Metal-organic framework (MOF) loaded with ionic liquids has brought new opportunities for solid-state batteries owing to its good interfacial compatibility and high ionic conductivity. MOF-808 is selected to be filled with Li-contained ionic liquid for structure and ion dynamics investigation using nuclear magnetic resonance (NMR) and X-ray diffraction. This study finds that the introduced ionic liquid would partially soften the matrix of MOF-808 and thus yield amorphous phase. By selective isotope replacement under cycling symmetric 6Li metal cell, Li+ ion is observed to mainly go cross ionic liquid in the open channel of matrix under potential polarization.
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