土耳其采石场天然粘土矿物样本中重金属浓度的测定

Aybaba Hançerli̇oğullari, Şeref Turhan, Arif Baştuğ, Y. G. A. Madee
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引用次数: 0

摘要

重金属对环境的污染正日益成为一个问题,并因其在世界各地造成的不利影响而备受关注。如今,由于人口快速增长、工业化和过度采矿活动而产生的各种化学、生物和物理污染物已成为一个重大问题,对世界各地的人类、动物、植物、生物和生态系统造成了不利影响。水云母是一种含有水合硅酸镁的粘土矿物,广泛应用于建筑、农业、食品、化肥、制药、洗涤剂、化妆品、油漆、造纸等领域。利用电离辐射X射线荧光光谱法,对从土耳其中安纳托利亚地区的三个采石场(Polatlı、Beylikova 和 Sivrihisar)采集的海泡石样本中分析发现,Al、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、As、Rb、Sr、Zr、Cd、Sn、Ba 和 Pb 的平均浓度分别为 5456.5、361.0、42.0、15.5、65.2、3831.5、8.6、23.7、7.8、11.8、5.3、13.7、1183.2、25.3、3.7、7.2、131.9 和 5.3 毫克/千克。V、Cr、Co、Ni、Cu、Zn、As、Sr、Cd、Sn、Ba 和 Pb 的平均富集因子值表明,这些元素在海泡石中的富集程度从极低到极高不等。除 Beylikova 采石场外,用于评估海泡石样本中 PTE 可能造成的健康风险的非致癌风险指数值和致癌风险估计值均在可接受限值和安全范围之内。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Türkiye'deki Ocaklardan Alınan Doğal Kil Mineral Örneklerinde Ağır Metal Konsantrasyonlarının Belirlenmesi
Environmental pollution of heavy metals is increasingly becoming a problem and has become of great concern due to the adverse effects it is causing around the world. Today, various chemical, biological, and physical pollutants arising as a result of rapidpopulation growth, industrialization, and excessive mining activities have become a major problem that adversely affects people, animals, plants, organisms, and ecosystems all over the world. Sepiolite is a clay mineral containing hydrated magnesium silicate and widely used in construction, agriculture, food, fertilizer, pharmaceutical, detergent, cosmetics, paint, paper, etc. The average concentrations of Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Zr, Cd, Sn, Ba and Pb analyzed in sepiolite samples collected from three quarries (Polatlı, Beylikova, and Sivrihisar) located in the Central Anatolian Region of Turkey using EDXRF spectroscopy were found as 5456.5, 361.0, 42.0, 15.5, 65.2, 3831.5, 8.6, 23.7, 7.8, 11.8, 5.3, 13.7, 1183.2, 25.3, 3.7, 7.2, 131.9 and 5.3 mg/kg, respectively. The average enrichment factor values of V, Cr, Co, Ni, Cu, Zn, As, Sr, Cd, Sn, Ba, and Pb indicated minimal to extremely high enrichment in sepiolite. The values of non-carcinogenic risk index and cancer risk estimated to evaluate potentially health risks caused by PTEs in sepiolite samples were within the acceptable limit and the safe range except for the Beylikova quarry.
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