利用木质和农业废弃物生产腐熟生物质颗粒(TIChE2021)

W. Chaiwat, Pimonpan Inthapat, Suwanna Boontanon, Pensiri Prachakittikul, A. Ua, Supachai Jadsadajerm, Nattawut Setkit, Nakorn Worasuwannarak
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摘要

本研究比较性地研究了两种不同的生物质预处理组合工艺顺序,即先制粒再热解(PAT)和先制粒再热解(PBT),以生产热解生物质颗粒(TBP),这些生物质来自木质生物质,如白千层(LC)和橡胶木(RW),以及农业残留物,如稻草(RS)和甘蔗叶(SCL)。在这项研究中,每种样品都在 260-300°C 的高温下进行了 5 分钟的热处理。研究发现,木质生物质和农业残留物的质量产率均低于 63wt%,而 TBPs 的体积密度则高于 400kg/m3。在平衡含水量(EMC)分析方面,通过 PBT 方法制备的 TBPs 在 30°C 下保存 12 天后,其平衡含水量低于生颗粒。在热化学性质方面,在所有生物质中,TBPs 的 FC、%C 和 HHV 值均高于未加工的颗粒,且随烘烤温度的升高而升高。在比较 PAT 和 PBT 托烧颗粒的 TBPs 时,300°C 时 PBT 托烧颗粒的 HHVs 最高,为 27 兆焦耳/千克(SCL 样品),导致 H/C 和 O/C 比接近于褐煤的 H/C 和 O/C 比。此外,PAT 和 PBT 托烧球团的燃烧性能指标(Sn)低于生球团,显示出与煤和褐煤相似的特性。简而言之,本研究建议使用 PBT 预处理工艺生产高质量的固体燃料,特别是用于农业残留物(如沙化土地),以替代目前使用的煤炭。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
PRODUCTION OF TORREFIED BIOMASS PELLETS FROM WOODY AND AGRICULTURAL RESIDUES (TIChE2021)
Two different combined process sequences of biomass pretreatment between pelletization after torrefaction (PAT) and pelletization before torrefaction (PBT) were comparatively investigated to produce torrefied biomass pellets (TBP) from woody biomasses, e.g. Leucaena (LC) and rubberwood (RW), and agricultural residues, e.g. rice straw (RS) and sugarcane leaves (SCL). In this study, each sample was thermally treated at 260-300°C for 5 min during torrefaction process. It was found that both woody biomasses and agricultural residues had mass yield lower than 63wt%, while the bulk density of TBPs were improved higher than 400kg/m3. For equilibrium moisture content (EMC) analysis, TBPs via PBT method had lower EMC than raw pellet after being kept at 30°C for 12 days. For the thermochemical properties, the TBPs had higher FC, %C, and HHVs than raw pellets in all biomasses and increased with torrefaction temperature. When comparing the TBPs between PAT and PBT torrefied pellets, the HHVs of PBT torrefied pellets at 300°C were achieved highest at 27 MJ/kg for SCL sample, leading to lower H/C and O/C ratio closely to that of lignite. In addition, the combustion performance index (Sn) of PAT and PBT torrefied pellets was lower than raw pellets, showing a similar property as coal and lignite. Briefly, this study suggests using PBT pretreatment process to produce high quality solid fuel, particularly for agricultural residues such as SCL for a potential substitute of currently used coal.
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