纤维悬浮液在生产精细纤维素的研磨设备中的流动分析

L. V. Yurtayeva, Yuri D. Alashkevich, Evgeniy Vyacheslavovich Kaplev, Dar'ya Yur'yevna Vasilyeva, Elena A. Slizikova
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引用次数: 0

摘要

在获取微晶纤维素的各种方法(机械法、化学法、热机械法、从溶液中提取粉末状纤维素)中,最常见的是纤维素的酸水解法。从植物原料中获取 MCC 的困难在于,除了纤维素之外,其成分中还含有木质素、半纤维素、各种萃取物质和微量矿物质等化合物。在水介质中研磨植物纤维时,既会发生改变纤维大小和形状的纯机械过程,也会发生称为纤维水合的胶体化学过程。机械现象表现为纤维缩短、纵向分裂成纤维状、外表面和表面游离羟基数量增加。水合指的是胶体化学现象,始于亲水性植物纤维的膨胀。 本文探讨了获得微晶纤维素的方法,以及在带有惯性体的研磨设备中从针叶树木种中分离出来的纤维悬浮液的发展影响因素。建立了纤维悬浮液在设备中流动的多物理模型。研究了研磨纤维悬浮液对获得细纤维素过程的影响。给出了成品的各项指标。根据 Shopper-Rigler 的不同研磨程度,分析了之前通过研磨阶段的纤维素聚合度的变化。提供了在获得细纤维素过程中降低成本和节约资源(酸浓度、温度和加工时间)的数据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ANALYSIS OF THE FLOW OF A FIBROUS SUSPENSION IN A GRINDING PLANT IN THE PRODUCTION OF FINE CELLULOSE
Of the various methods for obtaining microcrystalline cellulose (mechanical, chemical, thermomechanical, planting cellulose in powder form from its solutions), the most common is acid hydrolysis of cellulose. The difficulty of obtaining MCC from vegetable raw materials is that, in addition to cellulose, it contains in its composition such compounds as lignin, hemicelluloses, various extractive substances and an insignificant percentage of minerals. When grinding plant fibers in an aqueous medium, both a purely mechanical process of changing the size and shape of fibers and a colloidal chemical process called fiber hydration occurs. Mechanical phenomena are expressed in the shortening of fibers, their longitudinal splitting into fibrils, an increase in the outer surface and the number of free hydroxyl groups on their surface. The term hydration refers to colloidal chemical phenomena that begin with the swelling of hydrophilic plant fibers. The paper considers methods for obtaining microcrystalline cellulose and factors influencing the development of a fibrous suspension isolated from coniferous wood species in a grinding plant with inertial bodies. Multiphysical models of the flow of fibrous suspension in the installation are constructed. A study of the effect of grinding a fibrous suspension on the process of obtaining fine cellulose was carried out. The indicators of the finished product are given. The change in the degree of polymerization of cellulose that has previously passed the grinding stage, with different degrees of grinding according to the Shopper-Rigler, is analyzed. Data on cost reduction and resource savings (acid concentration, temperature and processing time) in the process of obtaining fine cellulose are presented.
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