使用甲醇钠催化剂和浸渍 NaOH 的椰壳活性炭催化剂的生物柴油酯交换工艺

Meygi Rezablina, Mustain Zamhari, A. Zikri
{"title":"使用甲醇钠催化剂和浸渍 NaOH 的椰壳活性炭催化剂的生物柴油酯交换工艺","authors":"Meygi Rezablina, Mustain Zamhari, A. Zikri","doi":"10.32672/jse.v8i4.6773","DOIUrl":null,"url":null,"abstract":"Biodiesel is one of the renewable energies that can be obtained by converting triglycerides into methyl esters by transesterification process. Used cooking oil is heated with anhydrous methanol which is added with an acid catalyst or base catalyst. The catalyst has a role as a substance to reduce the activation energy of fatty acids in used cooking oil to increase the reaction rate. In this study, Sodium methoxidealkaline catalyst and NaOH-impregnated activated carbon base catalyst were used. Activated carbon catalyst using variation of concentration of activated carbon 1N, 2N, 3N, 4N, and 5N for 18 hours, 21 hours, and 24 hours and the use of sodium methoxidecatalyst with variation of oil: methanol ratio 1:3, 1:6, 1:9, 1:12, 1:15. The results showed that the biodiesel yield using carbon catalyst was 98.2%, 2% w/w catalyst with oil: methanol ratio 1:12 at 60℃ for 120 minutes. The best result of biodiesel using sodium methoxidecatalyst is 87.65%, catalyst 1.25% w/w with ratio 1:12, temperature 60℃ for 120 minutes. Keyword :  Active Carbon, Biodiesel, Catalyst, Sodium Methoxide, Transesterification","PeriodicalId":17758,"journal":{"name":"Jurnal Serambi Engineering","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Proses Transesterifikasi Biodiesel Menggunakan Katalis Sodium Methoxide Dan Katalis Berbasis Karbon Aktif Dari Tempurung Kelapa Yang Diimpregnasi NaOH\",\"authors\":\"Meygi Rezablina, Mustain Zamhari, A. Zikri\",\"doi\":\"10.32672/jse.v8i4.6773\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Biodiesel is one of the renewable energies that can be obtained by converting triglycerides into methyl esters by transesterification process. Used cooking oil is heated with anhydrous methanol which is added with an acid catalyst or base catalyst. The catalyst has a role as a substance to reduce the activation energy of fatty acids in used cooking oil to increase the reaction rate. In this study, Sodium methoxidealkaline catalyst and NaOH-impregnated activated carbon base catalyst were used. Activated carbon catalyst using variation of concentration of activated carbon 1N, 2N, 3N, 4N, and 5N for 18 hours, 21 hours, and 24 hours and the use of sodium methoxidecatalyst with variation of oil: methanol ratio 1:3, 1:6, 1:9, 1:12, 1:15. The results showed that the biodiesel yield using carbon catalyst was 98.2%, 2% w/w catalyst with oil: methanol ratio 1:12 at 60℃ for 120 minutes. The best result of biodiesel using sodium methoxidecatalyst is 87.65%, catalyst 1.25% w/w with ratio 1:12, temperature 60℃ for 120 minutes. Keyword :  Active Carbon, Biodiesel, Catalyst, Sodium Methoxide, Transesterification\",\"PeriodicalId\":17758,\"journal\":{\"name\":\"Jurnal Serambi Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-10-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Jurnal Serambi Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.32672/jse.v8i4.6773\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Jurnal Serambi Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.32672/jse.v8i4.6773","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

生物柴油是可再生能源之一,可通过酯交换过程将甘油三酯转化为甲酯。将废食用油与无水甲醇一起加热,然后加入酸催化剂或碱催化剂。催化剂的作用是降低废食用油中脂肪酸的活化能,从而提高反应速度。本研究使用了甲醇钠碱性催化剂和 NaOH 浸渍活性炭碱性催化剂。使用活性炭催化剂时,活性炭的浓度分别为 1N、2N、3N、4N 和 5N,时间分别为 18 小时、21 小时和 24 小时;使用甲氧基化钠催化剂时,油与甲醇的比例分别为 1:3、1:6、1:9、1:12 和 1:15。结果表明,使用碳催化剂的生物柴油产量为 98.2%,使用 2% w/w 催化剂、油与甲醇的比例为 1:12、60 ℃、120 分钟的生物柴油产量为 98.2%。使用甲氧基化钠催化剂生产生物柴油的最佳结果是 87.65%,催化剂的重量百分比为 1.25%,比例为 1:12,温度为 60℃,时间为 120 分钟。关键词 :活性碳 生物柴油 催化剂 甲醇钠 酯交换反应
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Proses Transesterifikasi Biodiesel Menggunakan Katalis Sodium Methoxide Dan Katalis Berbasis Karbon Aktif Dari Tempurung Kelapa Yang Diimpregnasi NaOH
Biodiesel is one of the renewable energies that can be obtained by converting triglycerides into methyl esters by transesterification process. Used cooking oil is heated with anhydrous methanol which is added with an acid catalyst or base catalyst. The catalyst has a role as a substance to reduce the activation energy of fatty acids in used cooking oil to increase the reaction rate. In this study, Sodium methoxidealkaline catalyst and NaOH-impregnated activated carbon base catalyst were used. Activated carbon catalyst using variation of concentration of activated carbon 1N, 2N, 3N, 4N, and 5N for 18 hours, 21 hours, and 24 hours and the use of sodium methoxidecatalyst with variation of oil: methanol ratio 1:3, 1:6, 1:9, 1:12, 1:15. The results showed that the biodiesel yield using carbon catalyst was 98.2%, 2% w/w catalyst with oil: methanol ratio 1:12 at 60℃ for 120 minutes. The best result of biodiesel using sodium methoxidecatalyst is 87.65%, catalyst 1.25% w/w with ratio 1:12, temperature 60℃ for 120 minutes. Keyword :  Active Carbon, Biodiesel, Catalyst, Sodium Methoxide, Transesterification
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信