由一些碱金属原子和甘氨酸酐合成的两种新型霍夫曼类化合物及其特性

Z. Kartal, Z. Şahin
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引用次数: 0

摘要

本研究合成了两种新化合物,前者为晶体状,后者为粉末状,其封闭式分别为 C8H10K2N6NiO4 和 C8H10Na2N6NiO4。通过 SC-XRD 和 FT-IR 方法对这些化合物的各种特性进行了表征。在高斯 03 程序的帮助下,获得了这些化合物的理论信息。最能反映第一种三维化合物结构特性的分子式为{K2(GA)(H2O)2[Ni(CN)4]}n。根据类似的思路,可以认为最能反映第二种三维化合物结构特性的分子式为 {Na2(GA)(H2O)2[Ni(CN)4]}n。{K2(GA)(H2O)2[Ni(μ4-CN)4]}n化合物的不对称单元由半个Ni(II)离子、一个K(I)阳离子、两个氰配体、半个GA配体分子和一个结合水配体分子组成。该化合物的结构由三维聚合链组成,由 GA 分子、K(I) 阳离子、水配体分子和 Ni(CN)4 离子之间的各种键形成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis And Characterization of Two New Hofmann-Type-Like Compounds From Some Alkali Metal Atoms And Glycine Anhydride
In this study, two new compounds with their closed formula, C8H10K2N6NiO4, and C8H10Na2N6NiO4, were synthesized, the first in crystal form and the second in powder form. Various properties of these compounds were characterized by SC-XRD and FT-IR methods. Theoretical information about the compounds was obtained with the help of the Gaussian 03 program. The molecular formula that best reflects the structural properties of this first 3D compound, which is in crystalline form and has polymeric properties, can be given as {K2(GA)(H2O)2[Ni(CN)4]}n. With a similar thought, it can be suggested that the molecular formula that best reflects the structural properties of the second 3D compound in powder form and with polymeric properties will be {Na2(GA)(H2O)2[Ni(CN)4]}n. The asymmetric unit of the {K2(GA)(H2O)2[Ni(μ4-CN)4]}n compound is composed of a half Ni(II) ion, one K(I) cation, two cyanide ligands, a half GA ligand molecule, and one bounded water ligand molecule. The structure of the compound, which consists of 3D polymeric chains, is formed by various bonds between the GA molecule, K(I) cations, water ligand molecules, and Ni(CN)4 ions.
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