Reham Mostafa, S. Mahmoud, N. Tantawy, Saad Mohamed
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引用次数: 0
摘要
必须研究和改进硫化镍钴电极的优异电化学性能。为了在超级电容器中储存能量,本研究以聚乙烯醇(PEI)为碳源,采用溶热技术制备了镍钴硫化镍(NiCo 2 S 4 /Ni/Ni 9 S 8)纳米结构复合材料(NCS/N/NS),然后在 500 °C 的氩气环境下退火一小时,再以硫脲为硫源和氮源进行水热法处理。NCS/N/NS 具有优异的电化学储能特性。当用于储能电池时,NCS/N/NS 制成的电极材料在 1 Ag -1 的条件下显示出 1620 Fg -1 (696 Cg -1 )的超强电容。通过使用 NCS/NS 作为带正电的电极和商用 AC 的对电极,创建了一个 NCS/NS// 活性碳 (AC) 不对称装置,并投入实际使用。该非对称装置实现了 53 Wh kg -1 的独特比能量,在 1 Ag -1 时的比功率为 887 W kg -1 。
Novel fabrication of a nanostructured NiCo2S4/Ni/Ni9S8 composite for energy storage applications
Superior electrochemical behavior for nickel-cobalt sulfide electrodes must be researched and improved. For the storage of energy in supercapacitors, this work, the NiCo 2 S 4 /Ni/Ni 9 S 8 nanostructure composite (NCS/N/NS) was created using a solvothermal technique using PEI as a carbon source, followed by argon atmosphere annealing at 500 °C for an hour, followed by a hydrothermal method using thiourea as a sulfur and nitrogen source. NCS/N/NS supplies exceptional electrochemical energy storage features. When used for SCs, the manufactured electrode material, NCS/N/NS, revealed at 1 Ag −1 a superb capacitance of 1620 Fg −1 (696 Cg −1 ). An NCS/N/NS//activated carbon (AC) asymmetric device was created for practical use by utilizing an NCS/N/NS as the positively charged electrode and the opposite electrode of commercial AC. The asymmetric device achieved a unique specific energy of 53 Wh kg −1 , with a specific power of 887 W kg −1 at 1 Ag −1 .