Lead isotopes in New England (USA) volcanogenic massive sulphide deposits: implications for metal sources and pre-accretionary tectonostratigraphic terranes

Lead isotope values for volcanogenic massive sulphide (VMS) deposits provide important insights into metal sources and the nature of pre-accretionary tectonostratigraphic terranes and underlying basements. Deposits of this type in New England formed in diverse tectonic settings including volcanic arcs and backarcs, a supra-subduction zone arc, a rifted fore-arc foreland basin, and a rifted continental margin. Following VMS mineralization on or near the seafloor, components of the tectonostratigraphic assemblages—volcanic ± sedimentary rocks, coeval intrusions, sulphide deposits, and underlying basements—were diachronously accreted to the Laurentian margin during the Paleozoic. Lead isotope data for galena show relatively large ranges for 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb. Evaluation of potential lead sources, using for comparison Pb-isotope data from modern and ancient settings, suggests that principal sources include the mantle, volcanic ± sedimentary rocks, and deeper basement rocks. Integration of the Pb-isotope values with published data such as Nd isotopes for the volcanic rocks and from deep seismic reflection profiles points to the involvement of several basements including those of Grenvillian, Ganderian, Avalonian, and West African (and/or Amazonian) affinity. Clustering of Pb-isotope data for VMS deposits within individual Cambrian and Ordovician volcanic and volcanosedimentary settings, delineated by differences in 206Pb/204Pb and µ (238U/204Pb) values, are consistent with lead derivation from at least four and possibly five different tectonostratigraphic assemblages with isotopically distinct basements. Collectively, our Pb-isotope data for New England VMS deposits provide a novel window into the nature of sub-arc basement rocks during pre-accretionary sulphide mineralization outboard of Laurentia during early Paleozoic time.