通过 Pd/G 复合材料提高 AZ31 合金的储氢能力

Song-Jeng Huang, Chen-Ju Lai, V. Rajagopal, Wen-Lie Chang
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引用次数: 0

摘要

本研究探讨了钯/石墨烯(Pd/G)对 AZ31 合金储氢的催化作用。采用 X 射线衍射(XRD)分析、扫描电子显微镜(SEM)和能量色散 X 射线光谱(SEM-EDS)确认了 AZ31 的均匀分布,并观察了与催化剂机械合金化后的相变。系统考察了 AZ31 与催化剂的储氢性能,并利用阿瓦拉米图确定了成核的最大反应速率时间。研究结果表明,加入 2% Pd/G 后,氢气吸收和解吸时间最快,最大 6.04 wt% 时需要 200 秒才能达到 90% 的储氢率。相应的最大氢气解吸时间为 694 秒,达到 6.03 wt%。因此,引入 2% Pd/G 催化剂被证明能有效地显著提高 AZ31 合金的氢吸收/解吸率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Enhancing Hydrogen Storage in AZ31 Alloy through Pd/G Composite
In this research, we investigated the catalytic effects of Palladium/Graphene(Pd/G) on AZ31 alloy for hydrogen storage. X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (SEM-EDS) were employed to confirm the homogeneous distribution of AZ31 and observe phase changes after mechanical alloying with the catalysts. The hydrogen storage properties of AZ31 with catalysts were systematically examined, and the time of maximum reaction rate for nucleation was determined using Avarami Plot. The results of the study show that the incorporation of 2% Pd/G resulted in the fastest hydrogen absorption and desorption time, taking 200 seconds to achieve 90% hydrogen storage with a maximum of 6.04 wt%. The corresponding maximum hydrogen desorption occurred in 694 seconds, reaching 6.03 wt%. Consequently, the introduction of 2% Pd/G catalyst proved to be effective in significantly enhancing the hydrogen ab/desorption rates of AZ31 alloy.
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