{"title":"大陆下岩石圈地幔中大量稀土元素的储存是由断裂作用而非熔融作用引发的","authors":"XinXiang Zhu, Yan Liu, Zengqian Hou","doi":"10.1130/g51102.1","DOIUrl":null,"url":null,"abstract":"Rare earth elements (REEs) are essential metals for modern technologies. Recent studies suggest that subcontinental lithospheric mantle (SCLM) remelting, previously fertilized by subducted marine sediments, leads to formation of REE-bearing rocks. However, the transfer mechanism of REE-rich sediments from the subducted slab to the overlying mantle wedge is unclear. We present high-pressure experiments on natural REE-rich marine sediments at 3–4 GPa and 800–1000 °C to constrain the phase relations, sediment melting behavior, and REE migration during subduction. Our results show recrystallization into an eclogite-like assemblage, with melting only occurring at 4 GPa, 1000 °C, experiments. Regardless of melting behavior, REE are refractory and mostly hosted by apatite. Buoyancy calculations suggest that most of the eclogite-like residues would form solid-state diapirs, ascending to the SCLM, resulting in the REE-fertilized source. Such flux may be required for substantial REE transport during subduction, as a foundation for economic-grade mineralization.","PeriodicalId":503125,"journal":{"name":"Geology","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Massive rare earth element storage in sub-continental lithospheric mantle initiated by diapirism, not by melting\",\"authors\":\"XinXiang Zhu, Yan Liu, Zengqian Hou\",\"doi\":\"10.1130/g51102.1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Rare earth elements (REEs) are essential metals for modern technologies. Recent studies suggest that subcontinental lithospheric mantle (SCLM) remelting, previously fertilized by subducted marine sediments, leads to formation of REE-bearing rocks. However, the transfer mechanism of REE-rich sediments from the subducted slab to the overlying mantle wedge is unclear. We present high-pressure experiments on natural REE-rich marine sediments at 3–4 GPa and 800–1000 °C to constrain the phase relations, sediment melting behavior, and REE migration during subduction. Our results show recrystallization into an eclogite-like assemblage, with melting only occurring at 4 GPa, 1000 °C, experiments. Regardless of melting behavior, REE are refractory and mostly hosted by apatite. Buoyancy calculations suggest that most of the eclogite-like residues would form solid-state diapirs, ascending to the SCLM, resulting in the REE-fertilized source. Such flux may be required for substantial REE transport during subduction, as a foundation for economic-grade mineralization.\",\"PeriodicalId\":503125,\"journal\":{\"name\":\"Geology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-11-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Geology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1130/g51102.1\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Geology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1130/g51102.1","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
稀土元素(REEs)是现代技术所必需的金属。最近的研究表明,大陆下岩石圈地幔(SCLM)重熔,以前由俯冲海洋沉积物肥化,导致含稀土元素岩石的形成。然而,富含REE的沉积物从俯冲板块到上覆地幔楔的转移机制尚不清楚。我们对富含REE的天然海洋沉积物在3-4 GPa和800-1000 °C的条件下进行了高压实验,以对俯冲过程中的相关系、沉积物熔融行为和REE迁移进行约束。我们的结果表明,只有在 4 GPa、1000 °C 的实验中才会发生熔融,从而重结晶成类似黝帘石的集合体。无论熔化行为如何,REE 都是难熔的,并且主要由磷灰石寄存。浮力计算表明,大部分类黝帘石残留物将形成固态二阶梯,上升到SCLM,形成REE肥化源。这种通量可能是俯冲过程中REE大量迁移所必需的,是经济品位矿化的基础。
Massive rare earth element storage in sub-continental lithospheric mantle initiated by diapirism, not by melting
Rare earth elements (REEs) are essential metals for modern technologies. Recent studies suggest that subcontinental lithospheric mantle (SCLM) remelting, previously fertilized by subducted marine sediments, leads to formation of REE-bearing rocks. However, the transfer mechanism of REE-rich sediments from the subducted slab to the overlying mantle wedge is unclear. We present high-pressure experiments on natural REE-rich marine sediments at 3–4 GPa and 800–1000 °C to constrain the phase relations, sediment melting behavior, and REE migration during subduction. Our results show recrystallization into an eclogite-like assemblage, with melting only occurring at 4 GPa, 1000 °C, experiments. Regardless of melting behavior, REE are refractory and mostly hosted by apatite. Buoyancy calculations suggest that most of the eclogite-like residues would form solid-state diapirs, ascending to the SCLM, resulting in the REE-fertilized source. Such flux may be required for substantial REE transport during subduction, as a foundation for economic-grade mineralization.