利用鲶鱼脂肪副产品合成生物基础油

Q4 Engineering

ARPN Journal of Engineering and Applied Sciences Pub Date : 2023-12-11 DOI:10.59018/1023265

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引用次数: 0

摘要

在这项研究中，鲶鱼脂肪副产品被用作合成生物基础油的原料。研究探讨了各种参数对反应产率的影响。在（H2O2/CH3COOH/C=C）摩尔比为 4.5/1.5/1.0、温度为 50 摄氏度、反应时间为 3 小时的条件下，产率为 91.2%。在（醋酐/环氧）摩尔比为 1.5/1.0、温度为 95 oC、反应时间为 4.5 小时的条件下，环氧与醋酐开环反应的产率达到 90.2%。通过傅立叶变换红外光谱和 1H-NMR 光谱分析方法确定了鲶鱼油起始原料、环氧鲶鱼油和聚酯鲶鱼油最终产品的主要官能团。观察结果表明，鲶鱼油与 H2O2 和 CH3COOH 的混合物发生了强烈的环氧化反应，与 (CH3CO)2O 和 H2SO4 催化剂发生了强烈的环氧开环反应，得到的鲶鱼聚酯油产品可作为矿物基础油的替代品和环保产品。

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Utilization of catfish fat by-products for the biological base oils synthesis

In this work, catfish fat by-product was utilized as feedstock in the synthesis of biological base oils. The study performs the effect of parameters on the reaction yield. 91.2% in (H2O2/CH3COOH/C=C) molar ratio of 4.5/1.5/1.0, the temperature of 50 oC, and 3 hours reaction time. The yield of the ring-opening reaction of epoxy with acetic anhydride reached at 90.2% in (acetic anhydride/epoxy) molar ratio of 1.5/1.0, the temperature of 95 oC, and 4.5 hours reaction time. The main functional groups of catfish oil starting material, epoxy catfish oil, and polyester catfish oil final product were identified by FT-IR and 1H-NMR spectral analysis methods. The observed results show that the catfish oil epoxidation reaction with a mixture of H2O2 and CH3COOH and the ring-opening reaction of epoxy with (CH3CO)2O, H2SO4 catalyst has occurred strongly and obtained product of catfish polyester oil could use as an alternative to mineral base oils and an environmentally friendly product.

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来源期刊

ARPN Journal of Engineering and Applied Sciences Engineering-Engineering (all)

CiteScore

0.70

自引率

0.00%

发文量

期刊介绍： ARPN Journal of Engineering and Applied Sciences (ISSN 1819-6608) is an online peer-reviewed International research journal aiming at promoting and publishing original high quality research in all disciplines of engineering sciences and technology. All research articles submitted to ARPN-JEAS should be original in nature, never previously published in any journal or presented in a conference or undergoing such process across the globe. All the submissions will be peer-reviewed by the panel of experts associated with particular field. Submitted papers should meet the internationally accepted criteria and manuscripts should follow the style of the journal for the purpose of both reviewing and editing. Our mission is -In cooperation with our business partners, lower the world-wide cost of research publishing operations. -Provide an infrastructure that enriches the capacity for research facilitation and communication, among researchers, college and university teachers, students and other related stakeholders. -Reshape the means for dissemination and management of information and knowledge in ways that enhance opportunities for research and learning and improve access to scholarly resources. -Expand access to research publishing to the public. -Ensure high-quality, effective and efficient production and support good research and development activities that meet or exceed the expectations of research community. Scope of Journal of Engineering and Applied Sciences: -Engineering Mechanics -Construction Materials -Surveying -Fluid Mechanics & Hydraulics -Modeling & Simulations -Thermodynamics -Manufacturing Technologies -Refrigeration & Air-conditioning -Metallurgy -Automatic Control Systems -Electronic Communication Systems -Agricultural Machinery & Equipment -Mining & Minerals -Mechatronics -Applied Sciences -Public Health Engineering -Chemical Engineering -Hydrology -Tube Wells & Pumps -Structures