以 CuCo2O4 纳米复合材料为活性吸附剂表面吸附去除碱性富春红染料

IF 1.2 Q3 MULTIDISCIPLINARY SCIENCES
A. A. Kadhim, Muneer. A . AL-Da'amy, Salah H. Kadhim, E. Kareem
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引用次数: 0

摘要

本研究涉及 CuCo2O4 尖晶石型纳米复合材料的合成。该材料采用共沉淀法合成,并通过傅立叶变换红外光谱(FTIR)、X 射线衍射(XRD)、场发射扫描电子显微镜(FESEM)和原子力显微镜(AFM)进行了表征。通过吸附去除水溶液中的碱性品红(BF)染料,研究了合成材料的活性。研究了不同的吸附参数,包括吸附剂表面的剂量、吸附时间、介质的 pH 值和温度。在接触时间为 5 分钟、表面吸附剂剂量为 0.005 克、pH 值为 8 和染料浓度为 50 毫克/升-1 时,最佳去除率约为 97%。L-1 的染料浓度时,最佳去除率约为 97%。 还对所制备材料吸附该染料的热力学参数进行了研究,如自由能(∆G)为负值。焓(∆H)为正值,表明吸附是自发的、内热的;熵(∆S)为正值,表明吸附剂对吸附剂的亲和力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Removing Basic Fuchsine Dye by Adsorption over CuCo2O4 Nanocomposite as an Active Adsorbent Surface
This study involves the synthesis of CuCo2O4 spinel-type nanocomposite. This material was synthesized using the co-precipitation method and characterized by Fourier Transform Infrared Spectroscopy (FTIR), X-rays Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), and Atomic Force Microscopy (AFM). The activity of the synthesized materials was investigated by following removing basic fuchsine (BF) dye from its aqueous solution by adsorption. Different adsorption parameters were conducted involving the dose of adsorbent surface, time of adsorption, pH of the medium, and temperature. The optimum removal efficiency was around 97 % at contact time 5 minutes, 0.005g of dose the surface adsorbent, pH = 8 and 50 mg. L-1 concentration of dye.  Thermodynamic parameters for the adsorption of this dye over the prepared materials were also conducted such as free energy (∆G) negative. While enthalpy (∆H) positive which indicates the adsorption was spontaneous and endothermic, also entropy (∆S) was positive shows the affinity of the adsorbent towards the adsorbate.
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来源期刊
Baghdad Science Journal
Baghdad Science Journal MULTIDISCIPLINARY SCIENCES-
CiteScore
2.00
自引率
50.00%
发文量
102
审稿时长
24 weeks
期刊介绍: The journal publishes academic and applied papers dealing with recent topics and scientific concepts. Papers considered for publication in biology, chemistry, computer sciences, physics, and mathematics. Accepted papers will be freely downloaded by professors, researchers, instructors, students, and interested workers. ( Open Access) Published Papers are registered and indexed in the universal libraries.
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